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Intercalation-deposition mechanism induced by aligned carbon fiber toward dendrite-free metallic potassium batteries
Xiao, Kuikui1; Wu, Jian Fang1; Yan, Hanghang2; Mo, Ying1; Zhou, Wang1; Peng, Yufan1; Chen, Shi3; Cui, Xiangyang2; Chen, Lei4; Xu, Chaohe5; Liu, Jilei1
2022-10-01
Source PublicationEnergy Storage Materials
ISSN2405-8297
Volume51Pages:122-129
Abstract

Metallic potassium (K) anodes are highly desirable for high energy density batteries. However, challenges lie in uncontrollable dendrite growth and/or inevitable generation of dead K. Here, composite anodes are constructed by covering a layer of aligned carbon fiber on the surface of each metallic K anode (K-ACF). Symmetrical K-ACF//K-ACF cells can work stably without short circuit for over 600 h, which is quite longer than cells using composite anodes with unaligned carbon fiber (K-UCF) and bare metallic K anodes. Comprehensive characterizations reveal a stepwise intercalation-deposition process on the K-ACF anode during the K plating, and the intercalation is proved to be necessary for the uniform K flux due to the improved potassiophility of potassiated ACF. Besides, the aligned structure of ACF offers a uniform current density and K ion flux on the surface of composite anodes, promoting the stable K stripping/plating. The K-ACF//Prussian blue (PB) cell exhibits a high discharge capacity of 83.6 mAh g (267.4 Wh kg based on the mass of PB) under a charge/discharge rate of 200 mA g with a capacity loss rate of 0.044% per cycle. This work opens up a new avenue toward high energy and dendrite-free potassium batteries.

KeywordAligned Carbon Fiber Composite Anode Intercalation-deposition Potassiophility Potassium Metal Anode
DOI10.1016/j.ensm.2022.06.033
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000827259600002
PublisherElsevier B.V.
Scopus ID2-s2.0-85133637448
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorLiu, Jilei
Affiliation1.College of Materials Science and Engineering, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, Hunan, 410082, China
2.State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Hunan, 410082, China
3.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau, 999078, China
4.Department of Mechanical Engineering, University of Michigan-Dearborn, Dearborn, 48128-1491, United States
5.College of Aerospace Engineering, Chongqing University, Chongqing, 400044, China
Recommended Citation
GB/T 7714
Xiao, Kuikui,Wu, Jian Fang,Yan, Hanghang,et al. Intercalation-deposition mechanism induced by aligned carbon fiber toward dendrite-free metallic potassium batteries[J]. Energy Storage Materials, 2022, 51, 122-129.
APA Xiao, Kuikui., Wu, Jian Fang., Yan, Hanghang., Mo, Ying., Zhou, Wang., Peng, Yufan., Chen, Shi., Cui, Xiangyang., Chen, Lei., Xu, Chaohe., & Liu, Jilei (2022). Intercalation-deposition mechanism induced by aligned carbon fiber toward dendrite-free metallic potassium batteries. Energy Storage Materials, 51, 122-129.
MLA Xiao, Kuikui,et al."Intercalation-deposition mechanism induced by aligned carbon fiber toward dendrite-free metallic potassium batteries".Energy Storage Materials 51(2022):122-129.
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