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Temperature-dependent structure and magnetization of YCrO3 compound
Qian Zhao1,2; Ying-Hao Zhu1,3; Si Wu1,3; Jun-Chao Xia1,3; Peng-Fei Zhou1; Kai-Tong Sun1; Hai-Feng Li1
2022-06-01
Source PublicationChinese Physics B
ISSN1674-1056
Volume31Issue:4Pages:046101
Abstract

We have grown a YCrO3 single crystal by the floating-zone method and studied its temperature dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well indexed by an orthorhombic structure with space group of Pbnm (No. 62). From 36 to 300 K, no structural phase transition occurs in the pulverized YCrO3 single crystal. The antiferromagnetic phase transition temperature was determined as TN = 141.58(5) K by the magnetization versus temperature measurements. We found weak ferromagnetic behavior in the magnetic hysteresis loops below TN. Especially, we demonstrated that the antiferromagnetism and weak ferromagnetism appear simutaniously upon cooling. The lattice parameters (a, b, c, and V ) deviate downward from the Grueneisen law, displaying an anisotropic magnetostriction effect. We extracted temperature variation of the local distortion parameter ∆. Compared to the ∆ value of Cr ions, Y, O1, and O2 ions show one order of magnitude larger ∆ values indicative of much stronger local lattice distortions. Moreover, the calculated bond valence states of Y and O2 ions have obvious subduction charges.

KeywordOrthochromates X-ray Powder Diffraction Crystal Structure Magnetization
DOI10.1088/1674-1056/ac2b23
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaPhysics
WOS SubjectPhysics, Multidisciplinary
WOS IDWOS:000806529300001
PublisherInstitute of Physics
The Source to ArticlePB_Publication
Scopus ID2-s2.0-85132318686
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Co-First AuthorQian Zhao
Corresponding AuthorHai-Feng Li
Affiliation1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macao SAR 999078, China
2.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
3.Guangdong–Hong Kong–Macao Joint Laboratory for Neutron Scattering Science and Technology, DongGuan 523803, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Qian Zhao,Ying-Hao Zhu,Si Wu,et al. Temperature-dependent structure and magnetization of YCrO3 compound[J]. Chinese Physics B, 2022, 31(4), 046101.
APA Qian Zhao., Ying-Hao Zhu., Si Wu., Jun-Chao Xia., Peng-Fei Zhou., Kai-Tong Sun., & Hai-Feng Li (2022). Temperature-dependent structure and magnetization of YCrO3 compound. Chinese Physics B, 31(4), 046101.
MLA Qian Zhao,et al."Temperature-dependent structure and magnetization of YCrO3 compound".Chinese Physics B 31.4(2022):046101.
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