Residential College | false |
Status | 已發表Published |
Temperature-dependent structure and magnetization of YCrO3 compound | |
Qian Zhao1,2; Ying-Hao Zhu1,3; Si Wu1,3; Jun-Chao Xia1,3; Peng-Fei Zhou1; Kai-Tong Sun1; Hai-Feng Li1 | |
2022-06-01 | |
Source Publication | Chinese Physics B |
ISSN | 1674-1056 |
Volume | 31Issue:4Pages:046101 |
Abstract | We have grown a YCrO3 single crystal by the floating-zone method and studied its temperature dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well indexed by an orthorhombic structure with space group of Pbnm (No. 62). From 36 to 300 K, no structural phase transition occurs in the pulverized YCrO3 single crystal. The antiferromagnetic phase transition temperature was determined as TN = 141.58(5) K by the magnetization versus temperature measurements. We found weak ferromagnetic behavior in the magnetic hysteresis loops below TN. Especially, we demonstrated that the antiferromagnetism and weak ferromagnetism appear simutaniously upon cooling. The lattice parameters (a, b, c, and V ) deviate downward from the Grueneisen law, displaying an anisotropic magnetostriction effect. We extracted temperature variation of the local distortion parameter ∆. Compared to the ∆ value of Cr ions, Y, O1, and O2 ions show one order of magnitude larger ∆ values indicative of much stronger local lattice distortions. Moreover, the calculated bond valence states of Y and O2 ions have obvious subduction charges. |
Keyword | Orthochromates X-ray Powder Diffraction Crystal Structure Magnetization |
DOI | 10.1088/1674-1056/ac2b23 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Physics |
WOS Subject | Physics, Multidisciplinary |
WOS ID | WOS:000806529300001 |
Publisher | Institute of Physics |
The Source to Article | PB_Publication |
Scopus ID | 2-s2.0-85132318686 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Co-First Author | Qian Zhao |
Corresponding Author | Hai-Feng Li |
Affiliation | 1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macao SAR 999078, China 2.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China 3.Guangdong–Hong Kong–Macao Joint Laboratory for Neutron Scattering Science and Technology, DongGuan 523803, China |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Qian Zhao,Ying-Hao Zhu,Si Wu,et al. Temperature-dependent structure and magnetization of YCrO3 compound[J]. Chinese Physics B, 2022, 31(4), 046101. |
APA | Qian Zhao., Ying-Hao Zhu., Si Wu., Jun-Chao Xia., Peng-Fei Zhou., Kai-Tong Sun., & Hai-Feng Li (2022). Temperature-dependent structure and magnetization of YCrO3 compound. Chinese Physics B, 31(4), 046101. |
MLA | Qian Zhao,et al."Temperature-dependent structure and magnetization of YCrO3 compound".Chinese Physics B 31.4(2022):046101. |
Files in This Item: | There are no files associated with this item. |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment