This paper presents an experimental investigation on the material properties and cross-sectional behavior of 304L stainless steel tubular sections additively manufactured using selective laser melting (SLM). A total of 76 tensile coupons, 76 hardness test specimens, and 25 stub columns were fabricated from 304L stainless steel powders by the SLM technique. Tension coupon tests and hardness tests were conducted to determine the mechanical properties. Residual stresses and local geometric imperfections of the stub columns were measured. The effects of coupon specimen orientations, thicknesses, and annealing conditions on the measured material properties were explored. In addition, the failure modes, ultimate load-carrying capacities and structural responses of the stub columns with four different cross-sections under axial compression were obtained and analyzed to evaluate the cross-sectional behavior. The test results of ultimate strengths were compared with the predictions calculated from the current design methods. The test results showed that the tensile strength of the coupon perpendicular to the building direction was higher than that of the coupon parallel to the building direction. Moreover, the tensile strength of the coupon increased with the increase of the coupon thickness. Considering the cross-sectional behavior, the square hollow section (SHS) and circular hollow section (CHS) had greater cross-sectional axial capacities than the rectangular hollow section (RHS) and elliptical hollow section (EHS), respectively. The introduction of a single stiffener in SHS and CHS reduced the load-carrying capacities to a certain extent.