Monitoring and forecasting of sintering temperature (ST) is vital for safe, stable, and efficient operation of rotary kiln production process. Due to the complex coupling and time-varying characteristics of process data collected by the distributed control system, its long-range prediction remains a challenge. In this article, we propose a multivariate time series forecasting model based on dynamic spatio-temporal graph attention network (GAT) to model time-varying spatio-temporal correlation between the process data and perform long-range forecasting of ST. Aiming at the problem that there is no preset graph structure for multivariate data, we first propose an adaptive adjacency matrix generation algorithm to construct an elementary graph structure for the process data. Then, we design a spatio-temporal graph attention module, which consists of a multihead GAT for extracting time-varying spatial features and a gated dilated convolutional network for temporal features. Finally, considering the different time delay and rhythm of each process variable, we use dynamic system analysis to estimate the delay time and rhythm of each variable to guide the selection of dilation rates in dilated convolutional layers. The application results based on actual data show that the method has high prediction accuracy, and has broad application prospects in industrial processes.