hree‐dimensional (3D) printing has become one of the promising technologies forthe development of bulk‐sized nanomaterial composites for electrocatalysis.However, traditional methods such as field deposition modeling and stereolitho-graphy are not suitable for the development of functionalized materials for practicaluse. A large number of studies have focused on the development of the direct inkwriting (DIW) printing technique for the fabrication of graphene aerogel (GA)‐based electrodes with binders for electrocatalysis. Only a few studies have focusedon the synthesis of GA materials from binder‐free graphene oxide (GO) using theDIW 3D printing method. Here, we describe the preparation of GA‐basedelectrodes (without size contraction) with different Pd–Pt loadings using the DIWprinting method with a commercial 3D food printer. The electron microscopyresults showed that a Pd–Pt/GA monolith with a high Pd–Pt loading (59.43 wt%)could  be  obtained.  The  DIW‐printed  Pd–Pt/GA‐2  electrode  showed  goodelectrochemical performance in glucose electrooxidation (GOR), with a highoutput current density of 0.94 A g−1in 0.3M glucose/1M NaOH solution at the3000th cycle operation (60 h). This study shows the potential of DIW‐printedbinder‐free Pd–Pt/GA electrodes for use in fuel cell applications.