Residential College | false |
Status | 已發表Published |
Phononic transport in 1T′-MoTe2: Anisotropic structure with an isotropic lattice thermal conductivity | |
Cui, Xiangyue1; Yan, Xuefei1,2,3; Wang, Bowen1; Cai, Yongqing1![]() ![]() | |
2022-10-13 | |
Source Publication | Applied Surface Science
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ISSN | 0169-4332 |
Volume | 608Pages:155238 |
Abstract | Molybdenum ditelluride (MoTe) is an unique transition metal dichalcogenide owing to its energetically comparable 1H and 1T′ phases. This implies a high chance of coexistence of 1H/1T′ heterostructures which poses great complexity in the measurement of the intrinsic lattice thermal conductivities (κ). In this work, via first-principles calculations, we examine the lattice-wave propagation and thermal conduction in this highly structurally anisotropic 1T′ MoTe. Our calculation shows that the 1T′ phase has a sound velocity of 2.13 km/s (longitudinal acoustic wave), much lower than that of the 1H phase (4.05 km/s), indicating a staggered transmission of lattice waves across the boundary from 1H to 1T′ phase. Interestingly, the highly anisotropic 1T′ MoTe shows nearly isotropic and limited κ of 13.02 W/mK, owing to a large Grüneisen parameter of acoustic flexural mode, heavy masses of Mo and Te elements and a low phonon group velocity. Accumulative κ as a function of mean free path (MFP) indicates phonons with MFP less than ∼ 300 nm contribute 80 % of κ and an inflection point at ∼ 600 nm. Our results will be critical for understanding of the size dependent κ of nanostructured 1T′ MoTe. |
Keyword | Lattice Dynamics Monolayer Mote2 Strain Thermal Transport |
DOI | 10.1016/j.apsusc.2022.155238 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Materials Science ; Physics |
WOS Subject | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
WOS ID | WOS:000875411600002 |
Publisher | ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS |
Scopus ID | 2-s2.0-85139841379 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Cai, Yongqing |
Affiliation | 1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Macao 2.School of Microelectronics Science and Technology, Sun Yat-Sen University, Zhuhai, 519082, China 3.Guangdong Provincial Key Laboratory of Optoelectronic Information Processing Chips and Systems, Sun Yat-Sen University, Zhuhai, 519082, China |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Cui, Xiangyue,Yan, Xuefei,Wang, Bowen,et al. Phononic transport in 1T′-MoTe2: Anisotropic structure with an isotropic lattice thermal conductivity[J]. Applied Surface Science, 2022, 608, 155238. |
APA | Cui, Xiangyue., Yan, Xuefei., Wang, Bowen., & Cai, Yongqing (2022). Phononic transport in 1T′-MoTe2: Anisotropic structure with an isotropic lattice thermal conductivity. Applied Surface Science, 608, 155238. |
MLA | Cui, Xiangyue,et al."Phononic transport in 1T′-MoTe2: Anisotropic structure with an isotropic lattice thermal conductivity".Applied Surface Science 608(2022):155238. |
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