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Status | 已發表Published |
Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells | |
Liu, Jing1,2; Yin, Yanfeng1,3; He, Bingchen4,5; Wang, Pengfei1; Wang, Minhuan1; Cai, Wanxian2; Han, Yaling1,2; Su, Zhenhuang4; Guo, Jingya2; Cai, Rui6; Jin, Shengye3; Gao, Xingyu4; Bian, Jiming1; Shi, Yantao2 | |
2023-03-11 | |
Source Publication | Materials Today Physics |
ISSN | 2542-5293 |
Volume | 33Pages:101041 |
Abstract | Rapid progress has been made to achieve high power conversion efficiency (PCE) of metal halide perovskite solar cells in recent years. However, the unsatisfying operational stability still acts as the key factor that obstructs their successful commercialization. Although numerous strategies including grain boundary passivation, surface post-treatment, and processing management have been widely applied to enhance the stability of the perovskite solar cells with n-i-p structure, the significance of the bottom contact between electron transport layer (ETL) and perovskite is usually overlooked. Herein, we report a SnO ETL embedded with carbon quantum dots (CQDs) that largely improves the bottom interface between the perovskite layer and ETL. The multiple positive effect of CQDs in interfacial modulation were confirm by a variety of sophisticated characterizations. The PCE increased from 21.62% to 24.05% owing to the facilitated charge extraction. Notably, the perovskite solar cells with the CQD-SnO ETL retained over 84% of their initial PCE after 1000-h continuous irradiation under 1-sun illumination by suppressing the perovskite degradation starting from the bottom contact. This work provides a facile and efficient interface modification method for improving the performance and operational stability of FAPbI-based PSCs. |
Keyword | Perovskite Solar Cells Carbon Quantum Dots Electron Transport Layer Interfacial Coupling |
DOI | 10.1016/j.mtphys.2023.101041 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Materials Science ; Physics |
WOS Subject | Materials Science, Multidisciplinary ; Physics, Applied |
WOS ID | WOS:000952047500001 |
Publisher | ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS |
Scopus ID | 2-s2.0-85150073713 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Co-First Author | Liu, Jing; Yin, Yanfeng |
Corresponding Author | Wang, Minhuan; Bian, Jiming; Shi, Yantao |
Affiliation | 1.Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics, Dalian University of Technology, Dalian, Liaoning, 116024, China 2.State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, Department of Chemistry, School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning, 116024, China 3.State Key Laboratory of Molecular Reaction Dynamics and Dynamics Research Center for Energy and Environmental Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, 116023, China 4.Shanghai Synchrotron Radiation Facility (SSRF), Zhangjiang Laboratory, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 239 Zhangheng Road, 201204, China 5.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau, 999078, China 6.Instrumental Analysis Center, Dalian University of Technology, Dalian, Liaoning, 116024, China |
Recommended Citation GB/T 7714 | Liu, Jing,Yin, Yanfeng,He, Bingchen,et al. Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells[J]. Materials Today Physics, 2023, 33, 101041. |
APA | Liu, Jing., Yin, Yanfeng., He, Bingchen., Wang, Pengfei., Wang, Minhuan., Cai, Wanxian., Han, Yaling., Su, Zhenhuang., Guo, Jingya., Cai, Rui., Jin, Shengye., Gao, Xingyu., Bian, Jiming., & Shi, Yantao (2023). Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells. Materials Today Physics, 33, 101041. |
MLA | Liu, Jing,et al."Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells".Materials Today Physics 33(2023):101041. |
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