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Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells
Liu, Jing1,2; Yin, Yanfeng1,3; He, Bingchen4,5; Wang, Pengfei1; Wang, Minhuan1; Cai, Wanxian2; Han, Yaling1,2; Su, Zhenhuang4; Guo, Jingya2; Cai, Rui6; Jin, Shengye3; Gao, Xingyu4; Bian, Jiming1; Shi, Yantao2
2023-03-11
Source PublicationMaterials Today Physics
ISSN2542-5293
Volume33Pages:101041
Abstract

Rapid progress has been made to achieve high power conversion efficiency (PCE) of metal halide perovskite solar cells in recent years. However, the unsatisfying operational stability still acts as the key factor that obstructs their successful commercialization. Although numerous strategies including grain boundary passivation, surface post-treatment, and processing management have been widely applied to enhance the stability of the perovskite solar cells with n-i-p structure, the significance of the bottom contact between electron transport layer (ETL) and perovskite is usually overlooked. Herein, we report a SnO ETL embedded with carbon quantum dots (CQDs) that largely improves the bottom interface between the perovskite layer and ETL. The multiple positive effect of CQDs in interfacial modulation were confirm by a variety of sophisticated characterizations. The PCE increased from 21.62% to 24.05% owing to the facilitated charge extraction. Notably, the perovskite solar cells with the CQD-SnO ETL retained over 84% of their initial PCE after 1000-h continuous irradiation under 1-sun illumination by suppressing the perovskite degradation starting from the bottom contact. This work provides a facile and efficient interface modification method for improving the performance and operational stability of FAPbI-based PSCs.

KeywordPerovskite Solar Cells Carbon Quantum Dots Electron Transport Layer Interfacial Coupling
DOI10.1016/j.mtphys.2023.101041
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaMaterials Science ; Physics
WOS SubjectMaterials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000952047500001
PublisherELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS
Scopus ID2-s2.0-85150073713
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Co-First AuthorLiu, Jing; Yin, Yanfeng
Corresponding AuthorWang, Minhuan; Bian, Jiming; Shi, Yantao
Affiliation1.Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics, Dalian University of Technology, Dalian, Liaoning, 116024, China
2.State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, Department of Chemistry, School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning, 116024, China
3.State Key Laboratory of Molecular Reaction Dynamics and Dynamics Research Center for Energy and Environmental Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, 116023, China
4.Shanghai Synchrotron Radiation Facility (SSRF), Zhangjiang Laboratory, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 239 Zhangheng Road, 201204, China
5.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau, 999078, China
6.Instrumental Analysis Center, Dalian University of Technology, Dalian, Liaoning, 116024, China
Recommended Citation
GB/T 7714
Liu, Jing,Yin, Yanfeng,He, Bingchen,et al. Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells[J]. Materials Today Physics, 2023, 33, 101041.
APA Liu, Jing., Yin, Yanfeng., He, Bingchen., Wang, Pengfei., Wang, Minhuan., Cai, Wanxian., Han, Yaling., Su, Zhenhuang., Guo, Jingya., Cai, Rui., Jin, Shengye., Gao, Xingyu., Bian, Jiming., & Shi, Yantao (2023). Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells. Materials Today Physics, 33, 101041.
MLA Liu, Jing,et al."Focusing on the bottom contact: Carbon quantum dots embedded SnO2 electron transport layer for high-performance and stable perovskite solar cells".Materials Today Physics 33(2023):101041.
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