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Optimizing Kinetics for Enhanced Potassium-Ion Storage in Carbon-Based Anodes
Yang, Keke1; Zhou, Wang1; Fu, Qingfeng1; Xiao, Lili1; Mo, Ying1; Ke, Jinlong1; Shen, Wenzhuo2; Wang, Zhiyong1,3; Tu, Jian4; Chen, Shi5; Gao, Peng1; Liu, Jilei1
2023-08-29
Source PublicationAdvanced Functional Materials
ISSN1616-301X
Volume33Issue:44Pages:2306190
Abstract

The sluggish kinetics in traditional graphite anode greatly limits its fast-charging capability, which is critically important for commercialization of potassium ion batteries (PIBs). Hard carbon possesses randomly oriented pseudo-graphitic crystallites, enabling homogeneous reaction current and superior rate performance. Herein, a series of hybrid anodes with different hard carbon/graphite ratios are prepared by uniformly mixing graphite and hard carbon with ball-milling. Comprehensive experimental results in combination phase-field simulations reveal that the hybrid anode possesses a homogeneous reaction current and an intriguing potential difference between K-adsorbed hard carbon and non-potassiated graphite. The homogeneous reaction current in the hybrid anode promotes sufficient utilization of electrode material, leading to an increase in the reversible capacity. The present potential difference between K-adsorbed hard carbon and non-potassiated graphite provides an additional electric field force that facilitates the diffusion of K from hard carbon into the nearest neighbor graphite. All these together, emphasize the synergistic effects between hard carbon and graphite in hybrid anodes toward satisfactory rate and cycling performance. The hybrid strategy proposed here is compatible with the commercial battery manufacturing, offering a practical pathway for the development of high-performance PIBs.

KeywordFast-charging Hybrid Anodes Potassium-ion Batteries Raman Mapping Storage Mechanism
DOI10.1002/adfm.202306190
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:001077294200001
PublisherWILEY-V C H VERLAG GMBHPOSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85168857981
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorLiu, Jilei
Affiliation1.College of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology of Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, China
2.School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China
3.Hunan Zhongke Shinzoom Technology Co., Ltd., Changsha, 4106082, China
4.LI-FUN Technology Co., Ltd., Zhuzhou, 4106082, China
5.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, 999078, Macao
Recommended Citation
GB/T 7714
Yang, Keke,Zhou, Wang,Fu, Qingfeng,et al. Optimizing Kinetics for Enhanced Potassium-Ion Storage in Carbon-Based Anodes[J]. Advanced Functional Materials, 2023, 33(44), 2306190.
APA Yang, Keke., Zhou, Wang., Fu, Qingfeng., Xiao, Lili., Mo, Ying., Ke, Jinlong., Shen, Wenzhuo., Wang, Zhiyong., Tu, Jian., Chen, Shi., Gao, Peng., & Liu, Jilei (2023). Optimizing Kinetics for Enhanced Potassium-Ion Storage in Carbon-Based Anodes. Advanced Functional Materials, 33(44), 2306190.
MLA Yang, Keke,et al."Optimizing Kinetics for Enhanced Potassium-Ion Storage in Carbon-Based Anodes".Advanced Functional Materials 33.44(2023):2306190.
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