Residential College | false |
Status | 已發表Published |
Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites | |
Yang, Cheng1; Wei, Qi2; Gong, Yiyang1; Long, Mingzhu1; Zhou, Guofu1; Xing, Guichuan2; Wu, Bo1 | |
2023-09-01 | |
Source Publication | Journal of Physical Chemistry Letters |
ISSN | 1948-7185 |
Volume | 14Issue:44Pages:10046 - 10053 |
Abstract | Low-dimensional lead halides have attracted increasing attention due to their potential application as single-component white-light emitters. These materials exhibit a complex emission spectral structure, ranging from free exciton narrowband emissions to self-trapped exciton broadband emissions. However, there is still no consensus for the underlying physical mechanism, especially in the spectrum with both narrowband and broadband emissions. Here we aim to elucidate the correlation between the emission spectrum and the exciton-phonon coupling in the mixed halide perovskite BAPb(BrCl). Our findings reveal that the interplay between exciton localization and delocalization results in an intermediate exciton-phonon coupling, leading to line shapes beyond the Huang-Rhys model for the self-trapped exciton. By incorporating the exciton motional effect, we establish a unified photophysical model describing the emission spectrum from the self-trapped exciton type to the free exciton type. These results provide essential insights into the mechanisms governing exciton-phonon interactions and offer ways to control white-light emission in two-dimensional perovskites. |
DOI | 10.1021/acs.jpclett.3c02346 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
WOS Subject | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical |
WOS ID | WOS:001096828800001 |
Publisher | AMER CHEMICAL SOC1155 16TH ST, NW, WASHINGTON, DC 20036 |
Scopus ID | 2-s2.0-85178341799 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Xing, Guichuan; Wu, Bo |
Affiliation | 1.Guangdong Provincial Key Laboratory of Optical Information Materials and Technology, Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, 510006, China 2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Avenida da Universidade, 999078, Macao |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Yang, Cheng,Wei, Qi,Gong, Yiyang,et al. Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites[J]. Journal of Physical Chemistry Letters, 2023, 14(44), 10046 - 10053. |
APA | Yang, Cheng., Wei, Qi., Gong, Yiyang., Long, Mingzhu., Zhou, Guofu., Xing, Guichuan., & Wu, Bo (2023). Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites. Journal of Physical Chemistry Letters, 14(44), 10046 - 10053. |
MLA | Yang, Cheng,et al."Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites".Journal of Physical Chemistry Letters 14.44(2023):10046 - 10053. |
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