UM  > INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Residential Collegefalse
Status已發表Published
Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites
Yang, Cheng1; Wei, Qi2; Gong, Yiyang1; Long, Mingzhu1; Zhou, Guofu1; Xing, Guichuan2; Wu, Bo1
2023-09-01
Source PublicationJournal of Physical Chemistry Letters
ISSN1948-7185
Volume14Issue:44Pages:10046 - 10053
Abstract

Low-dimensional lead halides have attracted increasing attention due to their potential application as single-component white-light emitters. These materials exhibit a complex emission spectral structure, ranging from free exciton narrowband emissions to self-trapped exciton broadband emissions. However, there is still no consensus for the underlying physical mechanism, especially in the spectrum with both narrowband and broadband emissions. Here we aim to elucidate the correlation between the emission spectrum and the exciton-phonon coupling in the mixed halide perovskite BAPb(BrCl). Our findings reveal that the interplay between exciton localization and delocalization results in an intermediate exciton-phonon coupling, leading to line shapes beyond the Huang-Rhys model for the self-trapped exciton. By incorporating the exciton motional effect, we establish a unified photophysical model describing the emission spectrum from the self-trapped exciton type to the free exciton type. These results provide essential insights into the mechanisms governing exciton-phonon interactions and offer ways to control white-light emission in two-dimensional perovskites.

DOI10.1021/acs.jpclett.3c02346
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:001096828800001
PublisherAMER CHEMICAL SOC1155 16TH ST, NW, WASHINGTON, DC 20036
Scopus ID2-s2.0-85178341799
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorXing, Guichuan; Wu, Bo
Affiliation1.Guangdong Provincial Key Laboratory of Optical Information Materials and Technology, Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, 510006, China
2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Avenida da Universidade, 999078, Macao
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Yang, Cheng,Wei, Qi,Gong, Yiyang,et al. Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites[J]. Journal of Physical Chemistry Letters, 2023, 14(44), 10046 - 10053.
APA Yang, Cheng., Wei, Qi., Gong, Yiyang., Long, Mingzhu., Zhou, Guofu., Xing, Guichuan., & Wu, Bo (2023). Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites. Journal of Physical Chemistry Letters, 14(44), 10046 - 10053.
MLA Yang, Cheng,et al."Correlated Self-Trapped Excitons and Free Excitons with Intermediate Exciton-Phonon Coupling in 2D Mixed-Halide Perovskites".Journal of Physical Chemistry Letters 14.44(2023):10046 - 10053.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yang, Cheng]'s Articles
[Wei, Qi]'s Articles
[Gong, Yiyang]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yang, Cheng]'s Articles
[Wei, Qi]'s Articles
[Gong, Yiyang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yang, Cheng]'s Articles
[Wei, Qi]'s Articles
[Gong, Yiyang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.