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Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries
Liang, Fanghua1,2; Dong, Huilong3; Dai, Jiamu1; He, Honggang1; Zhang, Wei1; Chen, Shi4; Lv, Dong5; Liu, Hui1; Kim, Ick Soo2; Lai, Yuekun6; Tang, Yuxin6; Ge, Mingzheng1,4
2024-01-26
Source PublicationAdvanced Science
ISSN2198-3844
Volume11Issue:4Pages:2306711
Abstract

The development of conversion-typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS composite (SnS@N-HPCNFs) for high-rate energy storage, where the ultrathin SnS nanosheets are nanoconfined in N-doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three-dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS, while their hierarchical porous structure facilitates rapid ion diffusion. Specifically, the anode delivers a remarkable specific capacity of 1935.50 mAh g at 0.1 C and excellent rate capability up to 30 C with a specific capacity of 289.60 mAh g. Meanwhile, at a high rate of 20 C, the electrode displays a high capacity retention of 84% after 3000 cycles and a long cycle life of 10 000 cycles. This work provides a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast-charging energy storage devices.

KeywordCharge Carrier Transfer Hollow Porous Carbon Nanofibers Lithium-ion Batteries Sns2 Nanosheets Ultrahigh Charging Rates
DOI10.1002/advs.202306711
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:001112732000001
PublisherWILEY, 111 RIVER ST, HOBOKEN 07030-5774, NJ
Scopus ID2-s2.0-85178241838
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorZhang, Wei; Lv, Dong; Ge, Mingzheng
Affiliation1.School of Textile & Clothing, Nantong University, Nantong, 226019, China
2.Faculty of Textile Science and Technology, Shinshu University, Ueda, Tokida 3-15-1, Nagano, 386-8567, Japan
3.School of Materials Engineering, Changshu Institute of Technology, Changshu, 215500, China
4.Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Macao
5.Department of Biomedical Sciences, City University of Hong Kong, 999077, Hong Kong
6.College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Liang, Fanghua,Dong, Huilong,Dai, Jiamu,et al. Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries[J]. Advanced Science, 2024, 11(4), 2306711.
APA Liang, Fanghua., Dong, Huilong., Dai, Jiamu., He, Honggang., Zhang, Wei., Chen, Shi., Lv, Dong., Liu, Hui., Kim, Ick Soo., Lai, Yuekun., Tang, Yuxin., & Ge, Mingzheng (2024). Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries. Advanced Science, 11(4), 2306711.
MLA Liang, Fanghua,et al."Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries".Advanced Science 11.4(2024):2306711.
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