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Ionic-conductive sodium titanate to boost sodium-ion transport kinetics of hard carbon anode in sodium-ion batteries
Wang, Feng1,2,3; Li, Fan1; Gong, Hao1; Zhang, Yanlei1; Liu, Xinyu1; Jiang, Zhenming1; Chen, Lian2; Huang, Jianying1; Zhang, Yanyan1; Jiang, Yinzhu4; Chen, Binmeng3; Tang, Yuxin1,2
2024-01-06
Source PublicationJournal of Alloys and Compounds
ISSN0925-8388
Volume981Pages:173668
Abstract

Hard carbon with abundant resources, low-cost, and high specific capacity, is a promising anode material for large-scale sodium-ion batteries. However, the poor rate performance of hard carbon suffers from serious challenges due to sluggish ion transport dynamic behavior, especially at low potential, in high power density of sodium-ion batteries. To address this issue, we introduce an ionic-conductive sodium-titanate into hard carbon to boost its sodium-ion transport kinetics via constructing a dual ionic-electronic conducting network in hard carbon anode. Benefiting from our design, the optimized hard carbon-sodium titanate electrode achieves high specific capacity of 137 mAh g at a high current density of 10 A g, compared to that of hard carbon of 25 mAh g at 10 A g. Remarkably, it also exhibits an excellent capacity retention of 71.4% at the current density of 2.0 A g after 800 cycles. This work presents a practical strategy for high-rate hard carbon design and provides valuable insights into the construction of high-rate anode for advanced sodium-ion batteries.

KeywordHard Carbon High Rate Ionic Conductivity Sodium Ion Batteries Sodium Titanate
DOI10.1016/j.jallcom.2024.173668
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:001180125500001
PublisherELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Scopus ID2-s2.0-85183944802
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorZhang, Yanyan; Tang, Yuxin
Affiliation1.College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
2.Qingyuan Innovation Laboratory, Quanzhou, 362801, China
3.Institute of Applied Physics and Materials Engineering, University of Macau, 999078, China
4.School of Materials Science and Engineering, State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Wang, Feng,Li, Fan,Gong, Hao,et al. Ionic-conductive sodium titanate to boost sodium-ion transport kinetics of hard carbon anode in sodium-ion batteries[J]. Journal of Alloys and Compounds, 2024, 981, 173668.
APA Wang, Feng., Li, Fan., Gong, Hao., Zhang, Yanlei., Liu, Xinyu., Jiang, Zhenming., Chen, Lian., Huang, Jianying., Zhang, Yanyan., Jiang, Yinzhu., Chen, Binmeng., & Tang, Yuxin (2024). Ionic-conductive sodium titanate to boost sodium-ion transport kinetics of hard carbon anode in sodium-ion batteries. Journal of Alloys and Compounds, 981, 173668.
MLA Wang, Feng,et al."Ionic-conductive sodium titanate to boost sodium-ion transport kinetics of hard carbon anode in sodium-ion batteries".Journal of Alloys and Compounds 981(2024):173668.
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