Characterization of debris flow is critical to both risk assessment and hazard mitigation. Recent technologies enable onsite environmental monitoring sensors for geological disaster monitoring. However, the spatiotemporal understanding of debris flow in remote mountainous areas is still limited due to difficulties in observation networks and its complex driving conditions. Here we apply a coupled surface–subsurface hydrological model to examine the characteristics of the water movements near debris flow sites in southwest China. Our approach captured the temporal dynamics of infiltration, redistribution of soil moisture, groundwater storage, and lateral groundwater fluxes. The lateral groundwater flux and groundwater storage were informative indicators in identifying debris flow location. Such informativeness was only effective when hourly dynamics were analysed. Our findings provide new insight into quantifying debris flow susceptibility. This study suggests that the coupled surface–subsurface watershed modelling approach can be informative for preliminary monitoring, planning and management of debris flow.