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Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries
Wang, Zixing1; Wu, Jian Fang1; Zhou, Wang1; Mo, Ying1; Chen, Shi2; Zhou, Tongyu3; Shen, Wenzhuo4; Ren, Bohua5; Huang, Peifeng3; Liu, Jilei1
2024-08
Source PublicationACS Energy Letters
ISSN2380-8195
Volume9Issue:9Pages:4534-4543
Abstract

The development of metallic K is seriously hampered by low melting point, high reactivity, and uncontrollable dendrite growth. Herein, benefiting from the super-potassiophility of CNTs (carbon nanotubes), K@CNT composite anodes are prepared via a rational fused-modeling approach, where CNTs build interconnected frameworks and K atoms are anchored on CNTs, inducing depressed atomic creeping and flowability at high temperatures. Thereby, K@CNT composite anodes deliver flexibility, processability (∼30 μm), and thermal stability (up to 300 °C). In particular, K@CNT composite anodes exhibit a conformal stripping and plating behavior along with the plane-structure of the CNT framework during charge-discharge processes under 10 mA cm-2 without dendrites. Moreover, the K@CNT // Prussian white full cells exhibit high rate performance (60.9 mAh g-1 at 3000 mA g-1), high energy density (187.3 Wh kg-1), and high-temperature stability. This work provides an avenue for designing high-performance metallic K anodes and for driving the commercialization of K-metal batteries.

KeywordCarbon Nanotubes Electrical Properties Electrochemical Cells Electrodes Potassium
DOI10.1021/acsenergylett.4c01982
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:001300374900001
PublisherAMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036
Scopus ID2-s2.0-85202209258
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Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorLiu, Jilei
Affiliation1.College of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology of Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, 410082
2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Macau, Avenida da Universidade, Taipa, 999078, Macao
3.State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Changsha, 410082, China
4.Department of Electronic Engineering, School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China
5.College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China
Recommended Citation
GB/T 7714
Wang, Zixing,Wu, Jian Fang,Zhou, Wang,et al. Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries[J]. ACS Energy Letters, 2024, 9(9), 4534-4543.
APA Wang, Zixing., Wu, Jian Fang., Zhou, Wang., Mo, Ying., Chen, Shi., Zhou, Tongyu., Shen, Wenzhuo., Ren, Bohua., Huang, Peifeng., & Liu, Jilei (2024). Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries. ACS Energy Letters, 9(9), 4534-4543.
MLA Wang, Zixing,et al."Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries".ACS Energy Letters 9.9(2024):4534-4543.
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