Residential College | false |
Status | 已發表Published |
Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries | |
Wang, Zixing1; Wu, Jian Fang1; Zhou, Wang1; Mo, Ying1; Chen, Shi2; Zhou, Tongyu3; Shen, Wenzhuo4; Ren, Bohua5; Huang, Peifeng3; Liu, Jilei1 | |
2024-08 | |
Source Publication | ACS Energy Letters |
ISSN | 2380-8195 |
Volume | 9Issue:9Pages:4534-4543 |
Abstract | The development of metallic K is seriously hampered by low melting point, high reactivity, and uncontrollable dendrite growth. Herein, benefiting from the super-potassiophility of CNTs (carbon nanotubes), K@CNT composite anodes are prepared via a rational fused-modeling approach, where CNTs build interconnected frameworks and K atoms are anchored on CNTs, inducing depressed atomic creeping and flowability at high temperatures. Thereby, K@CNT composite anodes deliver flexibility, processability (∼30 μm), and thermal stability (up to 300 °C). In particular, K@CNT composite anodes exhibit a conformal stripping and plating behavior along with the plane-structure of the CNT framework during charge-discharge processes under 10 mA cm-2 without dendrites. Moreover, the K@CNT // Prussian white full cells exhibit high rate performance (60.9 mAh g-1 at 3000 mA g-1), high energy density (187.3 Wh kg-1), and high-temperature stability. This work provides an avenue for designing high-performance metallic K anodes and for driving the commercialization of K-metal batteries. |
Keyword | Carbon Nanotubes Electrical Properties Electrochemical Cells Electrodes Potassium |
DOI | 10.1021/acsenergylett.4c01982 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Electrochemistry ; Energy & Fuels ; Science & Technology - Other Topics ; Materials Science |
WOS Subject | Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS ID | WOS:001300374900001 |
Publisher | AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 |
Scopus ID | 2-s2.0-85202209258 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Liu, Jilei |
Affiliation | 1.College of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology of Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, 410082 2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Macau, Avenida da Universidade, Taipa, 999078, Macao 3.State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Changsha, 410082, China 4.Department of Electronic Engineering, School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China 5.College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China |
Recommended Citation GB/T 7714 | Wang, Zixing,Wu, Jian Fang,Zhou, Wang,et al. Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries[J]. ACS Energy Letters, 2024, 9(9), 4534-4543. |
APA | Wang, Zixing., Wu, Jian Fang., Zhou, Wang., Mo, Ying., Chen, Shi., Zhou, Tongyu., Shen, Wenzhuo., Ren, Bohua., Huang, Peifeng., & Liu, Jilei (2024). Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries. ACS Energy Letters, 9(9), 4534-4543. |
MLA | Wang, Zixing,et al."Ultrathin K-C Composite Anode Enables Conformal Stripping/Plating for Dendrite-Free and High-Rate Potassium-Metal Batteries".ACS Energy Letters 9.9(2024):4534-4543. |
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