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Visible-Light-Excited Fluorescent Hydrogel Tapes for Dual-Channel Copper Ions Recognition
Yuan, Zihao1; Zhu, Canjie2; Huang, Guang3; Lei, Bing1; Wu, Mingmei1; Feng, Zhiyuan1; Yang, Zhiyong4; Wei, Qiang5; Meng, Guozhe1; Guo, Honglei1
2024-09
Source PublicationACS Applied Polymer Materials
ISSN2637-6105
Volume6Issue:17Pages:10467-10477
Abstract

Incorporating aggregation-induced emission (AIE) molecules into hydrogels that exhibit ion-responsive and visible light excitation while maintaining good luminescence is challenging. To address this, we designed an ion-sensitive fluorescent hydrogel using an aggregation-induced phase separation strategy. We synthesized a tetraphenylethylene derivative (TPEBPy) with a long-chain alkene and copolymerized it with hydroxyethyl methacrylate (HEMA) and acrylic acid (AAc) through free-radical copolymerization. Because of the extended π-conjugated structure and AIE effect of the TPEBPy molecules, the synthesized fluorescent p(HEMA-co-AAc-TPEBPy) hydrogels exhibit excitation in the visible range (415 nm).This strategy requires only 0.1 mol % of TPEBPy molecules to achieve a sensitive threshold for specific recognition of copper ions as low as 10-5 M. By analyzing the fluorescence lifetime results, we determined the distribution of fluorescent molecules within the hydrogel, distinguishing between the aggregated and dispersed states. Additionally, this fluorescent hydrogel demonstrates the capability for visual colorimetric and fluorescence dual-channel detection of copper ions.

KeywordAggregation-induced Emission Early Warning Of Corrosion Fluorescent Hydrogel Reusability Visible Light Excitation
DOI10.1021/acsapm.4c01622
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaMaterials Science ; Polymer Science
WOS SubjectMaterials Science, Multidisciplinary ; Polymer Science
WOS IDWOS:001308499200001
PublisherAMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036
Scopus ID2-s2.0-85202730352
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Citation statistics
Document TypeJournal article
CollectionFaculty of Science and Technology
Corresponding AuthorFeng, Zhiyuan; Yang, Zhiyong; Wei, Qiang; Meng, Guozhe; Guo, Honglei
Affiliation1.School of Chemical Engineering and Technology, Sun Yat-sen Universit, Zhuhai, 519082, China
2.School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510006, China
3.Faculty of Science and Technology, University of Macau, 999078, Macao
4.Key Laboratory for Polymeric Composite and Functional Materials, Ministry of Education, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, China
5.Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo, 315201, China
Recommended Citation
GB/T 7714
Yuan, Zihao,Zhu, Canjie,Huang, Guang,et al. Visible-Light-Excited Fluorescent Hydrogel Tapes for Dual-Channel Copper Ions Recognition[J]. ACS Applied Polymer Materials, 2024, 6(17), 10467-10477.
APA Yuan, Zihao., Zhu, Canjie., Huang, Guang., Lei, Bing., Wu, Mingmei., Feng, Zhiyuan., Yang, Zhiyong., Wei, Qiang., Meng, Guozhe., & Guo, Honglei (2024). Visible-Light-Excited Fluorescent Hydrogel Tapes for Dual-Channel Copper Ions Recognition. ACS Applied Polymer Materials, 6(17), 10467-10477.
MLA Yuan, Zihao,et al."Visible-Light-Excited Fluorescent Hydrogel Tapes for Dual-Channel Copper Ions Recognition".ACS Applied Polymer Materials 6.17(2024):10467-10477.
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