Residential College | false |
Status | 已發表Published |
Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst | |
Chen, Yixin1; Meng, Jun1; Xu, Miao1; Qiao, Lulu2; Liu, Di2; Kong, Youchao3; Hu, Xiaosai4; Liu, Qingju5; Chen, Mingpeng5; Lyu, Siliu1,6; Tong, Rui1,6; Pan, Hui2,7 | |
2024-09 | |
Source Publication | Advanced Functional Materials |
ISSN | 1616-301X |
Pages | 2413474 |
Abstract | Renewable energy-based electrocatalytic oxidation for hydrogen production in complex reaction environments such as industrial wastewater and human urine demands high-performing catalysts to conduct switchable urea oxidation reactions (UOR) and traditional oxygen evolution reactions (OER). Here, a novel bifunctional nanosheet electrocatalyst is reported, Ir-Ni3N, which exhibits excellent electrocatalytic activity for both OER and UOR under alkaline conditions. Specifically, the overpotentials at 100 mA cm-2 for OER and UOR are 1.59 and 1.37 V vs. reversible hydrogen electrode (RHE) respectively, which are superior to most of the recently reported nickel-based catalysts. Accordingly, a comprehensive mechanism for competitive catalytic activities of Ni and Ir sites in Ir-Ni3N and the switch between OER and UOR that guarantees consistent hydrogen production is proposed. This study provides a feasible strategy for continuous hydrogen production aided by reagent-adaptive electrocatalysts in urea-containing wastewater. |
Keyword | Bifunctional Nanosheet Electrocatalyst Continuous Hydrogen Production Oxygen Evolution Reaction Switch Urea Oxidation Reaction |
DOI | 10.1002/adfm.202413474 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
WOS Subject | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
WOS ID | WOS:001324905900001 |
Publisher | WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY |
Scopus ID | 2-s2.0-85205273162 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | Faculty of Science and Technology INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING DEPARTMENT OF PHYSICS AND CHEMISTRY |
Corresponding Author | Lyu, Siliu; Tong, Rui; Pan, Hui |
Affiliation | 1.Hubei Key Laboratory of Energy Storage and Power Battery, School of Mathematics, Physics and Optoelectronic Engineering, Hubei University of Automotive Technology, Shiyan, 442002, China 2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Macao 3.Department of Physics and Electronic Engineering, Yancheng Teachers University, Yancheng, 224002, China 4.College of Textiles and Clothing, Yancheng Institute of Technology, Yancheng, 224000, China 5.Yunnan Key Laboratory for Micro/Nano Materials & Technology, National Center for International Research on Photoelectric and Energy Materials, School of Materials and Energy, Yunnan University, Kunming, 650091, China 6.Key Laboratory of Automotive Power Train and Electronics, School of Automotive Engineering, Hubei University of Automotive Technology, Shiyan, 442002, China 7.Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, 999078, Macao |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING; Faculty of Science and Technology |
Recommended Citation GB/T 7714 | Chen, Yixin,Meng, Jun,Xu, Miao,et al. Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst[J]. Advanced Functional Materials, 2024, 2413474. |
APA | Chen, Yixin., Meng, Jun., Xu, Miao., Qiao, Lulu., Liu, Di., Kong, Youchao., Hu, Xiaosai., Liu, Qingju., Chen, Mingpeng., Lyu, Siliu., Tong, Rui., & Pan, Hui (2024). Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst. Advanced Functional Materials, 2413474. |
MLA | Chen, Yixin,et al."Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst".Advanced Functional Materials (2024):2413474. |
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