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Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst
Chen, Yixin1; Meng, Jun1; Xu, Miao1; Qiao, Lulu2; Liu, Di2; Kong, Youchao3; Hu, Xiaosai4; Liu, Qingju5; Chen, Mingpeng5; Lyu, Siliu1,6; Tong, Rui1,6; Pan, Hui2,7
2024-09
Source PublicationAdvanced Functional Materials
ISSN1616-301X
Pages2413474
Abstract

Renewable energy-based electrocatalytic oxidation for hydrogen production in complex reaction environments such as industrial wastewater and human urine demands high-performing catalysts to conduct switchable urea oxidation reactions (UOR) and traditional oxygen evolution reactions (OER). Here, a novel bifunctional nanosheet electrocatalyst is reported, Ir-Ni3N, which exhibits excellent electrocatalytic activity for both OER and UOR under alkaline conditions. Specifically, the overpotentials at 100 mA cm-2 for OER and UOR are 1.59 and 1.37 V vs. reversible hydrogen electrode (RHE) respectively, which are superior to most of the recently reported nickel-based catalysts. Accordingly, a comprehensive mechanism for competitive catalytic activities of Ni and Ir sites in Ir-Ni3N and the switch between OER and UOR that guarantees consistent hydrogen production is proposed. This study provides a feasible strategy for continuous hydrogen production aided by reagent-adaptive electrocatalysts in urea-containing wastewater.

KeywordBifunctional Nanosheet Electrocatalyst Continuous Hydrogen Production Oxygen Evolution Reaction Switch Urea Oxidation Reaction
DOI10.1002/adfm.202413474
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:001324905900001
PublisherWILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85205273162
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionFaculty of Science and Technology
INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
DEPARTMENT OF PHYSICS AND CHEMISTRY
Corresponding AuthorLyu, Siliu; Tong, Rui; Pan, Hui
Affiliation1.Hubei Key Laboratory of Energy Storage and Power Battery, School of Mathematics, Physics and Optoelectronic Engineering, Hubei University of Automotive Technology, Shiyan, 442002, China
2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Macao
3.Department of Physics and Electronic Engineering, Yancheng Teachers University, Yancheng, 224002, China
4.College of Textiles and Clothing, Yancheng Institute of Technology, Yancheng, 224000, China
5.Yunnan Key Laboratory for Micro/Nano Materials & Technology, National Center for International Research on Photoelectric and Energy Materials, School of Materials and Energy, Yunnan University, Kunming, 650091, China
6.Key Laboratory of Automotive Power Train and Electronics, School of Automotive Engineering, Hubei University of Automotive Technology, Shiyan, 442002, China
7.Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, 999078, Macao
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING;  Faculty of Science and Technology
Recommended Citation
GB/T 7714
Chen, Yixin,Meng, Jun,Xu, Miao,et al. Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst[J]. Advanced Functional Materials, 2024, 2413474.
APA Chen, Yixin., Meng, Jun., Xu, Miao., Qiao, Lulu., Liu, Di., Kong, Youchao., Hu, Xiaosai., Liu, Qingju., Chen, Mingpeng., Lyu, Siliu., Tong, Rui., & Pan, Hui (2024). Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst. Advanced Functional Materials, 2413474.
MLA Chen, Yixin,et al."Adaptive Active Site Turning for Superior OER and UOR on Ir-Ni3N Catalyst".Advanced Functional Materials (2024):2413474.
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