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Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape-memory properties for wearable electrical devices
Zeng, Guang2; Gao, Wenshuo1; Qiu, Weicheng1; Li, Guanling1; Chen, Shousen1; He, Xin1; Sun, Guoxing3; Yang, Weijia1; Xin, Yue1
2024-11-12
Source PublicationJournal of Materials Chemistry A
ISSN2050-7488
Volume12Issue:44Pages:30618-30628
Abstract

Ionogels have aroused great attention due to their unique advantages for constructing wearable devices. However, the mechanical properties and ion conductivity of ionogels are often negatively correlated in current research. Furthermore, integrating advanced functionalities such as self-healing and shape-memory into a robust and conductive ionogel remains challenging. Herein, we developed a polyzwitterionic ionogel through the copolymerization of zwitterionic [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) (SBMA) and acrylamide (AAm) in the ionic liquid (IL) 1-ethyl-3-methylimidazolium ethyl sulfate (EMIES). The facile ability of the polyacrylamide (PAM) segments to engage in hydrogen bonds makes them easily aggregated in EMIES, resulting in the formation of polymer-rich domains. In contrast, poly[2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) (PSBMA) segments combined with EMIES form a solvent-rich phase due to their good compatibility. Therefore, an interpenetrating phase-separated structure is produced during the polymerization. The polymer-rich phase can dissipate energy and provide high strength, while the solvent-rich phase enables an ionogel with high stretchability. Additionally, the zwitterionic groups on PSBMA can provide separate and continuous ion conductive pathways, facilitating ion transport. The resulting ionogel presents balanced mechanical and electrical properties with a high toughness of 2.7 MJ m and ion conductivity of 1.3 mS cm, as well as desirable self-healing ability, which are attributed to the synergy of its phase separation and zwitterionicity. The resulting PSBMA/PAAm ionogel demonstrated excellent performance as a temperature and strain sensor. Remarkably, the ionogel possessed outstanding shape-memory properties, making the ionogel able to be fixed on a human joint or object with nonzero Gaussian curvature and maintain the sensing functions. Therefore, the morphing ionogel-based sensor displays huge versatility and potential for detecting the signal variations for objects with sophisticated geometries.

DOI10.1039/d4ta04228j
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:001336760400001
PublisherROYAL SOC CHEMISTRY; THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Scopus ID2-s2.0-85209246526
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Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorXin, Yue
Affiliation1.School of Applied Physics and Materials, Wuyi University, Jiangmen, 22 Dongcheng Village, Guangdong, 529020, China
2.School of Materials Science and Engineering, Guangdong Ocean University, Yangjiang, 529500, China
3.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, 999078, Macao
Recommended Citation
GB/T 7714
Zeng, Guang,Gao, Wenshuo,Qiu, Weicheng,et al. Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape-memory properties for wearable electrical devices[J]. Journal of Materials Chemistry A, 2024, 12(44), 30618-30628.
APA Zeng, Guang., Gao, Wenshuo., Qiu, Weicheng., Li, Guanling., Chen, Shousen., He, Xin., Sun, Guoxing., Yang, Weijia., & Xin, Yue (2024). Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape-memory properties for wearable electrical devices. Journal of Materials Chemistry A, 12(44), 30618-30628.
MLA Zeng, Guang,et al."Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape-memory properties for wearable electrical devices".Journal of Materials Chemistry A 12.44(2024):30618-30628.
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