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Interactive issues and strategic solutions for aqueous Zn metal anodes
Shi Huifa1; Han Sa1; Hou Zhanghao1; Niu Shuzhang2; Li Qing3; Lan Hongbo1
Source PublicationJournal of Energy Chemistry
ISSN2095-4956
2024-12
Abstract

Aqueous zinc (Zn)-ion batteries (ZIBs) have garnered significant attention as promising energy storage devices, primarily due to their low cost, high power density, and excellent safety profile. However, the commercial viability of these batteries is hindered by several issues related to the Zn metal anode, including dendritic growth, hydrogen evolution reaction (HER), surface corrosion, and passivation. This review delves into the root causes and key factors influencing these challenges from both electrochemical thermodynamics and kinetics perspectives. Subsequently, viable strategies to mitigate these issues are systematically summarized, including Zn anode reconstruction, artificial solid-electrolyte interphase (SEI) protection, electrolyte formulation optimization, and separator functionalization. Recent research advancements are examined thoroughly, with a focus on the mechanisms behind these approaches and the resulting battery performance. The review also critically assesses the strengths and limitations of these solutions. Finally, we highlight crucial research directions aimed at advancing the practical application of Zn metal anodes in future aqueous ZIBs.

KeywordDendrite Growth Her Protection Strategies Surface Corrosion Zn Metal Anode
Language英語English
DOI10.1016/j.jechem.2024.11.051
URLView the original
Volume103
Pages163-187
WOS IDWOS:001394003400001
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS Research AreaChemistry ; Energy & Fuels ; Engineering
Indexed BySSCI
Scopus ID2-s2.0-85212550921
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Citation statistics
Document TypeReview article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorShi Huifa; Niu Shuzhang; Li Qing
Affiliation1.Shandong Engineering Research Center for Additive Manufacturing, Qingdao University of Technology, Shandong, Qingdao, 266520, China
2.College of New Materials and New Energies, Shenzhen Technology University, Guangdong, Shenzhen, 518118, China
3.Institute of Applied Physics and Materials Engineering, University of Macau, Macau, 999078, China
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Shi Huifa,Han Sa,Hou Zhanghao,et al. Interactive issues and strategic solutions for aqueous Zn metal anodes[J]. Journal of Energy Chemistry, 2024, 103, 163-187.
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