Drawing on the Psychology of Working Theory, the present study investigates whether and how mobility constraints and educational experiences predict access to future decent work among two samples of Chinese undergraduates. The results reveal that educational experiences are directly related to future decent work access, while also indirectly linked to future decent work access via career adaptability and work volition, respectively. In addition, both objective and subjective mobility constraints are not associated with future decent work access, yet they are indirectly linked to future decent work access through career adaptability and work volition, respectively. Moreover, subjective mobility constraints but not objective mobility constraints are indirectly linked to future decent work access through educational experiences. The results provide empirical evidence for the recent expansion of decent education and of the school-to-work transition expansion of the Psychology of Working Theory.