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Effect of boron on nitrogen doped p-type ZnO thin films
Zhao P.-C.3; Zhang Z.-Z.3; Yao B.2; Li B.-H.3; Wang S.-P.3; Jiang M.-M.3; Zhao D.-X.3; Shan C.-X.3; Liu L.3; Shen D.-Z.3
2014-07-03
Source PublicationFaguang Xuebao/Chinese Journal of Luminescence
ISSN1000-7032
Volume35Issue:7Pages:795-799
Abstract

A stable and repeatable p-type ZnO is the key to realize the practical applications of photoelectric devices. Nitrogen has been considered as a possible acceptor dopant for p-type ZnO for a long time. However, the low solubility of nitrogen acceptor at oxygen site in ZnO is considered to be one of the main obstacles for p-type ZnO. In this paper, B/N co-doped p-type ZnO thin films were grown on sapphire substrate by plasma-assisted molecular beam epitaxy. The effect of boron on the nitrogen doping was studied by comparing with the single nitrogen doped thin films. X-ray photoelectron spectroscopy demonstrated there exists boron and B-N bond in the ZnO thin film. Compared to the single N-doped sample, B/N codoped samples present much higher carrier density. And the ZnO:(B, N) thin films show stable p-type conduction in two years. It is attributed to the increase of solubility of nitrogen acceptor. It benefits from the strong B-N bonding and weak donor character of boron at zinc site. Boron will not bring strong compensation for acceptors. It suggests that boron is a good co-doping candidate for nitrogen doped ZnO thin films.

KeywordB/n Codoped Stable P-type Conduction Zno
DOI10.3788/fgxb20143507.0795
URLView the original
Language英語English
Scopus ID2-s2.0-84904406489
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Affiliation1.University of Chinese Academy of Sciences
2.Jilin University
3.Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zhao P.-C.,Zhang Z.-Z.,Yao B.,et al. Effect of boron on nitrogen doped p-type ZnO thin films[J]. Faguang Xuebao/Chinese Journal of Luminescence, 2014, 35(7), 795-799.
APA Zhao P.-C.., Zhang Z.-Z.., Yao B.., Li B.-H.., Wang S.-P.., Jiang M.-M.., Zhao D.-X.., Shan C.-X.., Liu L.., & Shen D.-Z. (2014). Effect of boron on nitrogen doped p-type ZnO thin films. Faguang Xuebao/Chinese Journal of Luminescence, 35(7), 795-799.
MLA Zhao P.-C.,et al."Effect of boron on nitrogen doped p-type ZnO thin films".Faguang Xuebao/Chinese Journal of Luminescence 35.7(2014):795-799.
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