The mission of this chapter is to present a framework of ideas concerning the expected form of knowledge sharing over the emerging Semantic Web. Of specific interest is the perspective of appreciative inquiry, which should accommodate the creation of some appreciative knowledge environments (AKE) based on the peculiar organizational concerns that would encourage or better institutionalize knowledge work among people of interest in an organization. The AKE idea is extensible to the building of virtual communities of practice (CoP) whose meta-data requirements have been so much facilitated in today’s Web technologies including the ideas of data ownership, software as services, and the socialization and co-creation of content, and it is increasingly visible that the AKE model of knowledge sharing is compatible for the need of virtual collaboration in today’s knowledge-centric organizations. The author’s investigation should provide a basis to think about the social dimension of today’s Semantic Web, in view of the generative potential of various appreciative processes of knowledge sharing among communities of practice distributed throughout an organization.