Residential College | false |
Status | 已發表Published |
Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance | |
Qing Zhu1; Lingmin Yao2; Rui Tong1; Dong Liu1; Kar Wei Ng1; Hui Pan1,3 | |
2019-09-28 | |
Source Publication | New Journal of Chemistry |
ISSN | 1144-0546 |
Volume | 43Issue:36Pages:14518-14526 |
Abstract | In this work, we demonstrate the synthesis of a composite architecture that is composed of nitrogen-doped carbon encapsulating cobalt and titanium nitride nanoparticles on carbon cloth (Co-TiN@NG-x/CC) for hydrogen evolution reaction and supercapacitor applications. The optimized electrocatalyst, Co-TiN@NG-2/CC, shows a low overpotential of ∼208 mV to drive a current density of 10 mA cm and long-Term durability in 1 M KOH. For the supercapacitor (SC), Co-TiN@NG-2/CC exhibits a capacitance of up to 189 mF cm at a current density of 0.5 mA cm and good rate capability. The capacitance can retain ca. 70% of the initial specific capacitance even after 1000 cycles at a current density of 1 mA cm. The enhanced hydrogen evolution reaction and supercapacitance are attributed to the synergistic effect between titanium nitride and Co nanoparticles in the N-doped carbon matrix, leading to increased active sites and electrical conductivity. |
DOI | 10.1039/c9nj03531a |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Multidisciplinary |
WOS ID | WOS:000486223200031 |
Scopus ID | 2-s2.0-85072319645 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Kar Wei Ng; Hui Pan |
Affiliation | 1.Joint Key Laboratory of the Ministry of Education,Institute of Applied Physics and Materials Engineering,University of Macau,Macao 2.School of Physics and Electronic Engineering,Guangzhou University,Guangzhou,510006,China 3.Department of Physics and Chemistry,Faculty of Science and Technology,University of Macau,Macao |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING; Faculty of Science and Technology |
Recommended Citation GB/T 7714 | Qing Zhu,Lingmin Yao,Rui Tong,et al. Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance[J]. New Journal of Chemistry, 2019, 43(36), 14518-14526. |
APA | Qing Zhu., Lingmin Yao., Rui Tong., Dong Liu., Kar Wei Ng., & Hui Pan (2019). Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance. New Journal of Chemistry, 43(36), 14518-14526. |
MLA | Qing Zhu,et al."Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance".New Journal of Chemistry 43.36(2019):14518-14526. |
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