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Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance
Qing Zhu1; Lingmin Yao2; Rui Tong1; Dong Liu1; Kar Wei Ng1; Hui Pan1,3
2019-09-28
Source PublicationNew Journal of Chemistry
ISSN1144-0546
Volume43Issue:36Pages:14518-14526
Abstract

In this work, we demonstrate the synthesis of a composite architecture that is composed of nitrogen-doped carbon encapsulating cobalt and titanium nitride nanoparticles on carbon cloth (Co-TiN@NG-x/CC) for hydrogen evolution reaction and supercapacitor applications. The optimized electrocatalyst, Co-TiN@NG-2/CC, shows a low overpotential of ∼208 mV to drive a current density of 10 mA cm and long-Term durability in 1 M KOH. For the supercapacitor (SC), Co-TiN@NG-2/CC exhibits a capacitance of up to 189 mF cm at a current density of 0.5 mA cm and good rate capability. The capacitance can retain ca. 70% of the initial specific capacitance even after 1000 cycles at a current density of 1 mA cm. The enhanced hydrogen evolution reaction and supercapacitance are attributed to the synergistic effect between titanium nitride and Co nanoparticles in the N-doped carbon matrix, leading to increased active sites and electrical conductivity.

DOI10.1039/c9nj03531a
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000486223200031
Scopus ID2-s2.0-85072319645
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorKar Wei Ng; Hui Pan
Affiliation1.Joint Key Laboratory of the Ministry of Education,Institute of Applied Physics and Materials Engineering,University of Macau,Macao
2.School of Physics and Electronic Engineering,Guangzhou University,Guangzhou,510006,China
3.Department of Physics and Chemistry,Faculty of Science and Technology,University of Macau,Macao
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING;  Faculty of Science and Technology
Recommended Citation
GB/T 7714
Qing Zhu,Lingmin Yao,Rui Tong,et al. Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance[J]. New Journal of Chemistry, 2019, 43(36), 14518-14526.
APA Qing Zhu., Lingmin Yao., Rui Tong., Dong Liu., Kar Wei Ng., & Hui Pan (2019). Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance. New Journal of Chemistry, 43(36), 14518-14526.
MLA Qing Zhu,et al."Cobalt/titanium nitride@N-doped carbon hybrids for enhanced electrocatalytic hydrogen evolution and supercapacitance".New Journal of Chemistry 43.36(2019):14518-14526.
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