Lead halide perovskites have attracted tremendous attention because of their impressive optoelectronic properties. However, the toxicity of lead remains a bottleneck for further commercial development. Two-dimensional Ruddlesden-Popper tin-based perovskites are lead-free and more stable compared to their three-dimensional counterparts, which have great potential in the optoelectronic device field. Herein, we demonstrate high-quality two-dimensional phenylethylammonium tin-iodide perovskite (PEASnI) thin films by using toluene as the antisolvent. Furthermore, the PeLED performance is greatly improved by replacing the PEAI spacer cation with 2-thiopheneethyllamine iodide (TEAI). As a result, a TEA-based PeLED device is achieved with a low turn-on voltage of 2.3 V, a maximum luminance of 322 cd m, and maximum external quantum efficiency of 0.62%, which are the highest efficiency and brightness for pure red (emission peak = 638 nm) tin-based PeLEDs to date.