To enhance the reversible capacity and cycle stability of MoS₂ as anode materials for sodium ion batteries (SIBs), we constructed a hybrid architecture composed of MoS₂ and TiO₂ nanosheets, linking with reduced graphene oxide (RGO) to another TiO₂/MoS₂ to form a nanoflower structure. Owing to layered RGO coupled with TiO₂/MoS₂ hybrid, such a composite offered interconnected conductive channels to short shuttle path of Na⁺ ions and favorable transport kinetics under charge/discharge cycling. Moreover, this unique structure showed a porous and hierarchical architecture, which not only buffered volume changes but also provided more electrochemical active sites during insertion/deintercalation processes of Na ions. Outstanding electrochemical performances were identified by the component matching effect among TiO₂, MoS₂ and RGO with a three-dimensional (3D) interconnected network, exhibiting a good reversible capacity of 616 mA h g⁻¹ after 100 cycles at 0.1 A g⁻¹, an excellent rate capability of 250 mA h g⁻¹ even at 5A g⁻¹ and a long cycling stability of 460 mA h g⁻¹ with a capacity fluctuation of 0.03% per cycle within 350 cycles at 1 A g⁻¹.