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In Situ Growth of MAPbBr3 Nanocrystals on Few-Layer MXene Nanosheets with Efficient Energy Transfer
Zhang,Zhipeng1; Li,Ying2; Liang,Chao1; Yu,Guannan2; Zhao,Jiafu3; Luo,Shaojuan2,3; Huang,Yang4; Su,Chenliang2; Xing,Guichuan1
2020-04
Source PublicationSmall
ISSN1613-6810
Volume16Issue:17
Abstract

The performance of perovskite nanocrystals (NCs) in optoelectronics and photocatalysis is severely limited by the presence of large amounts of crystal boundaries in NCs film that greatly restricts energy transfer. Creating heterostructures based on perovskite NCs and 2D materials is a common approach to improve the energy transport at the perovskite/2D materials interface. Herein, methylamine lead bromide (MAPbBr, MA: CHNH) perovskite NCs are homogeneously deposited on highly conductive few-layer MXene (TiCT) nanosheets to form heterostructures through an in situ solution growth method. An optimal mixed solvent ratio is essential to realize the growth of perovskite NCs on TiCT nanosheets. Time-resolved photoluminescence spectroscopy, transient absorption spectroscopy, and the photoresponse of electron- and hole-only photoelectric conversion devices reveal the interfacial energy transfer behavior within MAPbBr/TiCT heterostructures. The present investigation may provide a useful guide toward use of halide perovskite/2D material heterostructures in applications such as photocatalysis as well as optoelectronics.

KeywordEnergy Transfer Heterostructrues Metal Halide Perovskite Nanocrystals Mxene Nanosheets Solvent Engineering
DOI10.1002/smll.201905896
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000522076600001
PublisherWILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85082951548
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorLuo,Shaojuan; Su,Chenliang; Xing,Guichuan
Affiliation1.Joint Key Laboratory of the Ministry of Education,Institute of Applied Physics and Materials Engineering,University of Macau,Taipa,Avenida da Universidade,999078,Macao
2.International Collaborative Laboratory of 2D materials for Optoelectronic Science and Technology (ICL-2D MOST),Shenzhen University,Shenzhen,518060,China
3.School of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou,510006,China
4.Shenzhen Key Laboratory of Polymer Science and Technology,College of Materials Science and Engineering,Shenzhen University,Shenzhen,518060,China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Zhang,Zhipeng,Li,Ying,Liang,Chao,et al. In Situ Growth of MAPbBr3 Nanocrystals on Few-Layer MXene Nanosheets with Efficient Energy Transfer[J]. Small, 2020, 16(17).
APA Zhang,Zhipeng., Li,Ying., Liang,Chao., Yu,Guannan., Zhao,Jiafu., Luo,Shaojuan., Huang,Yang., Su,Chenliang., & Xing,Guichuan (2020). In Situ Growth of MAPbBr3 Nanocrystals on Few-Layer MXene Nanosheets with Efficient Energy Transfer. Small, 16(17).
MLA Zhang,Zhipeng,et al."In Situ Growth of MAPbBr3 Nanocrystals on Few-Layer MXene Nanosheets with Efficient Energy Transfer".Small 16.17(2020).
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