UM  > INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Residential Collegefalse
Status已發表Published
Effect of Zinc-Doping on the Reduction of the Hot-Carrier Cooling Rate in Halide Perovskites
Qi Wei1; Jun Yin2; Osman M. Bakr2; Ze Wang3; Chenhao Wang3; Omar F. Mohammed2; Li, Mingjie3; Xing, Guichuan1
2021-05-03
Source PublicationAngewandte Chemie - International Edition
ISSN1433-7851
Volume60Issue:19Pages:10957-10963
Abstract

The fast hot-carrier cooling process in the solar-absorbers fundamentally limits their photon-conversion efficiencies. It is highly desirable to develop a solar absorber with long-lived hot-carriers at sun-illumination intensity, which can be used to develop the hot-carrier solar cells with enhanced efficiency. Herein, we reveal that zinc-doped (0.34 %) halide perovskites have the slower hot-carrier cooling compared with the pristine sample through the transient absorption spectroscopy measurements and theoretical calculations. The hot-carrier energy loss rate at the low photoexcitation level of 10 cm is found to be ≈3 times smaller than that of un-doped perovskites for T=500 K hot carriers, and up to ten times when the hot-carrier temperature approaches the lattice temperature. The incorporation of zinc-dopant into perovskites can reduce the nonadiabatic couplings between conduction bands, which retards the photogenerated hot-carriers relaxation processes. Our findings present a practical strategy to slow down the hot-carrier cooling in perovskites at low carrier densities, which would be invaluable for the further development of practical hot-carrier photovoltaics based on perovskites.

DOI10.1002/anie.202100099
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000634969300001
PublisherWILEY-V C H VERLAG GMBH,POSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85103391825
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorOmar F. Mohammed; Li, Mingjie; Xing, Guichuan
Affiliation1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Morocco
2.Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia
3.Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Qi Wei,Jun Yin,Osman M. Bakr,et al. Effect of Zinc-Doping on the Reduction of the Hot-Carrier Cooling Rate in Halide Perovskites[J]. Angewandte Chemie - International Edition, 2021, 60(19), 10957-10963.
APA Qi Wei., Jun Yin., Osman M. Bakr., Ze Wang., Chenhao Wang., Omar F. Mohammed., Li, Mingjie., & Xing, Guichuan (2021). Effect of Zinc-Doping on the Reduction of the Hot-Carrier Cooling Rate in Halide Perovskites. Angewandte Chemie - International Edition, 60(19), 10957-10963.
MLA Qi Wei,et al."Effect of Zinc-Doping on the Reduction of the Hot-Carrier Cooling Rate in Halide Perovskites".Angewandte Chemie - International Edition 60.19(2021):10957-10963.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Qi Wei]'s Articles
[Jun Yin]'s Articles
[Osman M. Bakr]'s Articles
Baidu academic
Similar articles in Baidu academic
[Qi Wei]'s Articles
[Jun Yin]'s Articles
[Osman M. Bakr]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Qi Wei]'s Articles
[Jun Yin]'s Articles
[Osman M. Bakr]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.