Residential College | false |
Status | 已發表Published |
Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates | |
Wei, Qi1; Du, Bin1; Wu, Bo2; Guo, Jia1; Li, Ming jie2; Fu, Jianhui2; Zhang, Zhipeng1; Yu, Jianwei1; Hou, Tianyu1; Xing, Guichuan3; Sum, Tze Chien2; Huang, Wei1 | |
2017-12-15 | |
Source Publication | Advanced Optical Materials |
Volume | 5Issue:24 |
Abstract | Metal-halide perovskites are recently extensively investigated as light absorbing material in solar cells. The outstanding optoelectronic properties and tunable light emission of the perovskites also make them promising candidates for light emitting diodes and lasers. However, understanding the relevant mechanisms and processes of the dependence of perovskite light emission on temperature and crystal size is still challenging. Herein, the CHNHPbBr monocrystals of different sizes are uniformly excited by two-photon absorption at 800 nm (100 fs, 1 KHz). In contrast to the reported relative large exciton binding energy (≈76 meV) and spectrum clearly resolved excitonic absorption, the light emission origin in CHNHPbBr microcrystals at room temperature is unambiguously determined to be dominated by free electron–hole bimolecular recombination. The coherent light emission threshold of CHNHPbBr microcrystal increases with temperature, which is closely related to the temperature induced transition from exciton gas to free charge carriers. In addition, the coherent light emission threshold is found to decrease with the microcrystal size, which could be well interpreted by the interaction between the optical confinement, defect density, and cavity quantum electrodynamics effect. These results presented here may facilitate the development of perovskite light emitting diodes and lasers. |
Keyword | Amplified Spontaneous Emission Excitons And Free Carriers Microlasers Multiphoton Absorption Perovskites |
DOI | 10.1002/adom.201700809 |
URL | View the original |
Language | 英語English |
WOS ID | WOS:000418123300013 |
Scopus ID | 2-s2.0-85032902461 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | University of Macau |
Affiliation | 1.Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), Nanjing, 30 South Puzhu Road, 211816, China 2.Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University (NTU), Singapore, 21 Nanyang Link, 637371, Singapore 3.Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Macao |
Recommended Citation GB/T 7714 | Wei, Qi,Du, Bin,Wu, Bo,et al. Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates[J]. Advanced Optical Materials, 2017, 5(24). |
APA | Wei, Qi., Du, Bin., Wu, Bo., Guo, Jia., Li, Ming jie., Fu, Jianhui., Zhang, Zhipeng., Yu, Jianwei., Hou, Tianyu., Xing, Guichuan., Sum, Tze Chien., & Huang, Wei (2017). Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates. Advanced Optical Materials, 5(24). |
MLA | Wei, Qi,et al."Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates".Advanced Optical Materials 5.24(2017). |
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