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Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates
Wei, Qi1; Du, Bin1; Wu, Bo2; Guo, Jia1; Li, Ming jie2; Fu, Jianhui2; Zhang, Zhipeng1; Yu, Jianwei1; Hou, Tianyu1; Xing, Guichuan3; Sum, Tze Chien2; Huang, Wei1
2017-12-15
Source PublicationAdvanced Optical Materials
Volume5Issue:24
Abstract

Metal-halide perovskites are recently extensively investigated as light absorbing material in solar cells. The outstanding optoelectronic properties and tunable light emission of the perovskites also make them promising candidates for light emitting diodes and lasers. However, understanding the relevant mechanisms and processes of the dependence of perovskite light emission on temperature and crystal size is still challenging. Herein, the CHNHPbBr monocrystals of different sizes are uniformly excited by two-photon absorption at 800 nm (100 fs, 1 KHz). In contrast to the reported relative large exciton binding energy (≈76 meV) and spectrum clearly resolved excitonic absorption, the light emission origin in CHNHPbBr microcrystals at room temperature is unambiguously determined to be dominated by free electron–hole bimolecular recombination. The coherent light emission threshold of CHNHPbBr microcrystal increases with temperature, which is closely related to the temperature induced transition from exciton gas to free charge carriers. In addition, the coherent light emission threshold is found to decrease with the microcrystal size, which could be well interpreted by the interaction between the optical confinement, defect density, and cavity quantum electrodynamics effect. These results presented here may facilitate the development of perovskite light emitting diodes and lasers.

KeywordAmplified Spontaneous Emission Excitons And Free Carriers Microlasers Multiphoton Absorption Perovskites
DOI10.1002/adom.201700809
URLView the original
Language英語English
WOS IDWOS:000418123300013
Scopus ID2-s2.0-85032902461
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Document TypeJournal article
CollectionUniversity of Macau
Affiliation1.Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), Nanjing, 30 South Puzhu Road, 211816, China
2.Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University (NTU), Singapore, 21 Nanyang Link, 637371, Singapore
3.Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Macao
Recommended Citation
GB/T 7714
Wei, Qi,Du, Bin,Wu, Bo,et al. Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates[J]. Advanced Optical Materials, 2017, 5(24).
APA Wei, Qi., Du, Bin., Wu, Bo., Guo, Jia., Li, Ming jie., Fu, Jianhui., Zhang, Zhipeng., Yu, Jianwei., Hou, Tianyu., Xing, Guichuan., Sum, Tze Chien., & Huang, Wei (2017). Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates. Advanced Optical Materials, 5(24).
MLA Wei, Qi,et al."Two-Photon Optical Properties in Individual Organic–Inorganic Perovskite Microplates".Advanced Optical Materials 5.24(2017).
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