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Dialkylamines Driven Two-Step Recovery of NiOx/ITO Substrates for High-Reproducibility Recycling of Perovskite Solar Cells
Xiyuan Feng1,2; Shuangpeng Wang2,3; Qing Guo4; Yudong Zhu1; Jingwei Xiu1; Limin Huang4; Zikang Tang2,3; Zhubing He1
2021-05-13
Source PublicationJournal of Physical Chemistry Letters
ISSN1948-7185
Volume12Issue:19Pages:4735-4741
Abstract

Because of the toxicity of water-soluble lead, the recycling of organic-inorganic lead-halides perovskite solar cells (PSCs) has attracted increasing attention. Here, we report a highly reliable two-step process to recycle cost-dominated indium-tin-oxide (ITO) substrates coated with NiOx and regenerate their based PSCs by function of dialkylamines. The champion recycled PSC can achieve 20% in conversion-efficiency, higher than 17.92% of the fresh one. Strikingly, the regenerated devices can remain superior to the fresh ones in the first 7 of 10 recycles. The comprehensive X-ray photoelectronic spectroscopy analysis reveals that dipropylamine has a suitable interaction with NiOx surfaces by Ni-N coordination, enabling its effective interfacial passivation and template effect of high-quality growth of perovskites. That leads to the suppressed nonradiative recombination of both interfacial and bulk, and finally improves the device performances. The dialkylamines driven two-step recycling process offers a promising and highly reproducible strategy to recycle PSCs, especially the cost-dominated NiOx/ITO substrates.

DOI10.1021/acs.jpclett.1c00735
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000655640200033
PublisherAMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036
Scopus ID2-s2.0-85106361684
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Citation statistics
Document TypeJournal article
CollectionDEPARTMENT OF PHYSICS AND CHEMISTRY
Faculty of Science and Technology
INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorZhubing He
Affiliation1.Department of Materials Science and Engineering, Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG), Southern University of Science and Technology, Shenzhen, No. 1088, Xueyuan Road, 518055, China
2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Avenida da Universidade, 999078, Macao
3.Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, Taipa, Avenida da Universidade, 999078, Macao
4.Department of Chemistry, Southern University of Science and Technology, Shenzhen, No. 1088, Xueyuan Road, 518055, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Xiyuan Feng,Shuangpeng Wang,Qing Guo,et al. Dialkylamines Driven Two-Step Recovery of NiOx/ITO Substrates for High-Reproducibility Recycling of Perovskite Solar Cells[J]. Journal of Physical Chemistry Letters, 2021, 12(19), 4735-4741.
APA Xiyuan Feng., Shuangpeng Wang., Qing Guo., Yudong Zhu., Jingwei Xiu., Limin Huang., Zikang Tang., & Zhubing He (2021). Dialkylamines Driven Two-Step Recovery of NiOx/ITO Substrates for High-Reproducibility Recycling of Perovskite Solar Cells. Journal of Physical Chemistry Letters, 12(19), 4735-4741.
MLA Xiyuan Feng,et al."Dialkylamines Driven Two-Step Recovery of NiOx/ITO Substrates for High-Reproducibility Recycling of Perovskite Solar Cells".Journal of Physical Chemistry Letters 12.19(2021):4735-4741.
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