Residential College | false |
Status | 已發表Published |
Synthesis of functionalized siloles from Si-tethered diynes | |
Luo Q.1; Gu L.1; Wang C.1; Liu J.1; Zhang W.1; Xi Z.1 | |
2009-07-01 | |
Source Publication | Tetrahedron Letters |
ISSN | 00404039 |
Volume | 50Issue:26Pages:3213-3215 |
Abstract | A new synthetic itinerary to silole from Si-tethered diynes is reported. In this protocol, the Si-tethered diyne manifests definitely the reactivity of monoyne to form the lithio silole via zirconacyclopetadiene, 1,4-diiodo-1,3-butadiene, and the corresponding dilithiodiene successively. Lithio siloles thus obtained above could be easily functionalized to give various types of silole derivatives. Complex structure like bridged bis-silole compounds could also be constructed by this process. © 2009 Elsevier Ltd. All rights reserved. |
Keyword | 1,4-diiodo-1,3-butadiene 1,4-dilithio-1,3-butadiene Cleavage Of Si-c Bond Phenyl-bridged Bis-silole Si-tethered Diynes Silole Zirconacyclopetadiene |
DOI | 10.1016/j.tetlet.2009.01.152 |
URL | View the original |
Language | 英語English |
WOS ID | WOS:000267070700022 |
Scopus ID | 2-s2.0-65649115877 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | University of Macau |
Affiliation | 1.Peking University 2.Shanghai Institute of Organic Chemistry Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Luo Q.,Gu L.,Wang C.,et al. Synthesis of functionalized siloles from Si-tethered diynes[J]. Tetrahedron Letters, 2009, 50(26), 3213-3215. |
APA | Luo Q.., Gu L.., Wang C.., Liu J.., Zhang W.., & Xi Z. (2009). Synthesis of functionalized siloles from Si-tethered diynes. Tetrahedron Letters, 50(26), 3213-3215. |
MLA | Luo Q.,et al."Synthesis of functionalized siloles from Si-tethered diynes".Tetrahedron Letters 50.26(2009):3213-3215. |
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