Residential Collegefalse
Status已發表Published
A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols
Guo, Liya1,5; Gu, Wenjun1,5; Peng, Chao2,5; Wang, Weigang2; Jie Li, Yong3; Zong, Taomou4; Tang, Yujing1; Wu, Zhijun4; Lin, Qinhao1; Ge, Maofa2,5,6; Zhang, Guohua1; Hu, Min4; Bi, Xinhui1; Wang, Xinming1,5,6; Tang, Mingjin1,5,6
2019-02-18
Source PublicationAtmospheric Chemistry and Physics
ISSN1680-7316
Volume19Issue:4Pages:2115-2133
Abstract

Calcium- and magnesium-containing salts are important components for mineral dust and sea salt aerosols, but their physicochemical properties are not well understood yet. In this study, hygroscopic properties of eight Ca- and Mg-containing salts, including Ca(NO3)2ĝš4H2O, Mg(NO3)2ĝš6H2O, MgCl2ĝš6H2O, CaCl2ĝš6H2O, Ca(HCOO)2, Mg(HCOO)2ĝš2H2O, Ca(CH3COO)2ĝšH2O and Mg(CH3COO)2ĝš4H2O, were investigated using two complementary techniques. A vapor sorption analyzer was used to measure the change of sample mass with relative humidity (RH) under isotherm conditions, and the deliquescence relative humidities (DRHs) for temperature in the range of 5-30 ĝC as well as water-to-solute ratios as a function of RH at 5 and 25 ĝC were reported for these eight compounds. DRH values showed large variation for these compounds; for example, at 25 ĝC DRHs were measured to be ĝ1/4 28.5 % for CaCl2ĝš6H2O and >95 % for Ca(HCOO)2 and Mg(HCOO)2ĝš2H2O. We further found that the dependence of DRH on temperature can be approximated by the Clausius-Clapeyron equation. In addition, a humidity tandem differential mobility analyzer was used to measure the change in mobility diameter with RH (up to 90 %) at room temperature, in order to determine hygroscopic growth factors of aerosol particles generated by atomizing water solutions of these eight compounds. All the aerosol particles studied in this work, very likely to be amorphous under dry conditions, started to grow at very low RH (as low as 10 %) and showed continuous growth with RH. Hygroscopic growth factors at 90 % RH were found to range from 1.26 ± 0.04 for Ca(HCOO)2 to 1.79 ± 0.03 for Ca(NO3)2, and the single hygroscopicity parameter ranged from 0.09-0.13 for Ca(CH3COO)2 to 0.49-0.56 for Ca(NO3)2. Overall, our work provides a comprehensive investigation of hygroscopic properties of these Ca- and Mg-containing salts, largely improving our knowledge of the physicochemical properties of mineral dust and sea salt aerosols.

DOI10.5194/acp-19-2115-2019
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaEnvironmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
WOS SubjectEnvironmental Sciences ; Meteorology & Atmospheric Sciences
WOS IDWOS:000459023300002
Scopus ID2-s2.0-85061935549
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionDEPARTMENT OF CIVIL AND ENVIRONMENTAL ENGINEERING
Corresponding AuthorTang, Mingjin
Affiliation1.State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China
2.State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China
3.Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Taipa, Avenida da Universidade, Macao
4.State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
5.University of Chinese Academy of Sciences, Beijing, 100049, China
6.Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, China
Recommended Citation
GB/T 7714
Guo, Liya,Gu, Wenjun,Peng, Chao,et al. A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols[J]. Atmospheric Chemistry and Physics, 2019, 19(4), 2115-2133.
APA Guo, Liya., Gu, Wenjun., Peng, Chao., Wang, Weigang., Jie Li, Yong., Zong, Taomou., Tang, Yujing., Wu, Zhijun., Lin, Qinhao., Ge, Maofa., Zhang, Guohua., Hu, Min., Bi, Xinhui., Wang, Xinming., & Tang, Mingjin (2019). A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols. Atmospheric Chemistry and Physics, 19(4), 2115-2133.
MLA Guo, Liya,et al."A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols".Atmospheric Chemistry and Physics 19.4(2019):2115-2133.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Guo, Liya]'s Articles
[Gu, Wenjun]'s Articles
[Peng, Chao]'s Articles
Baidu academic
Similar articles in Baidu academic
[Guo, Liya]'s Articles
[Gu, Wenjun]'s Articles
[Peng, Chao]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Guo, Liya]'s Articles
[Gu, Wenjun]'s Articles
[Peng, Chao]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.