Residential College | false |
Status | 已發表Published |
A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols | |
Guo, Liya1,5; Gu, Wenjun1,5; Peng, Chao2,5; Wang, Weigang2; Jie Li, Yong3; Zong, Taomou4; Tang, Yujing1; Wu, Zhijun4; Lin, Qinhao1; Ge, Maofa2,5,6; Zhang, Guohua1; Hu, Min4; Bi, Xinhui1; Wang, Xinming1,5,6; Tang, Mingjin1,5,6 | |
2019-02-18 | |
Source Publication | Atmospheric Chemistry and Physics |
ISSN | 1680-7316 |
Volume | 19Issue:4Pages:2115-2133 |
Abstract | Calcium- and magnesium-containing salts are important components for mineral dust and sea salt aerosols, but their physicochemical properties are not well understood yet. In this study, hygroscopic properties of eight Ca- and Mg-containing salts, including Ca(NO3)2ĝš4H2O, Mg(NO3)2ĝš6H2O, MgCl2ĝš6H2O, CaCl2ĝš6H2O, Ca(HCOO)2, Mg(HCOO)2ĝš2H2O, Ca(CH3COO)2ĝšH2O and Mg(CH3COO)2ĝš4H2O, were investigated using two complementary techniques. A vapor sorption analyzer was used to measure the change of sample mass with relative humidity (RH) under isotherm conditions, and the deliquescence relative humidities (DRHs) for temperature in the range of 5-30 ĝC as well as water-to-solute ratios as a function of RH at 5 and 25 ĝC were reported for these eight compounds. DRH values showed large variation for these compounds; for example, at 25 ĝC DRHs were measured to be ĝ1/4 28.5 % for CaCl2ĝš6H2O and >95 % for Ca(HCOO)2 and Mg(HCOO)2ĝš2H2O. We further found that the dependence of DRH on temperature can be approximated by the Clausius-Clapeyron equation. In addition, a humidity tandem differential mobility analyzer was used to measure the change in mobility diameter with RH (up to 90 %) at room temperature, in order to determine hygroscopic growth factors of aerosol particles generated by atomizing water solutions of these eight compounds. All the aerosol particles studied in this work, very likely to be amorphous under dry conditions, started to grow at very low RH (as low as 10 %) and showed continuous growth with RH. Hygroscopic growth factors at 90 % RH were found to range from 1.26 ± 0.04 for Ca(HCOO)2 to 1.79 ± 0.03 for Ca(NO3)2, and the single hygroscopicity parameter ranged from 0.09-0.13 for Ca(CH3COO)2 to 0.49-0.56 for Ca(NO3)2. Overall, our work provides a comprehensive investigation of hygroscopic properties of these Ca- and Mg-containing salts, largely improving our knowledge of the physicochemical properties of mineral dust and sea salt aerosols. |
DOI | 10.5194/acp-19-2115-2019 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
WOS Subject | Environmental Sciences ; Meteorology & Atmospheric Sciences |
WOS ID | WOS:000459023300002 |
Scopus ID | 2-s2.0-85061935549 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | DEPARTMENT OF CIVIL AND ENVIRONMENTAL ENGINEERING |
Corresponding Author | Tang, Mingjin |
Affiliation | 1.State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China 2.State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China 3.Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Taipa, Avenida da Universidade, Macao 4.State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China 5.University of Chinese Academy of Sciences, Beijing, 100049, China 6.Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, China |
Recommended Citation GB/T 7714 | Guo, Liya,Gu, Wenjun,Peng, Chao,et al. A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols[J]. Atmospheric Chemistry and Physics, 2019, 19(4), 2115-2133. |
APA | Guo, Liya., Gu, Wenjun., Peng, Chao., Wang, Weigang., Jie Li, Yong., Zong, Taomou., Tang, Yujing., Wu, Zhijun., Lin, Qinhao., Ge, Maofa., Zhang, Guohua., Hu, Min., Bi, Xinhui., Wang, Xinming., & Tang, Mingjin (2019). A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols. Atmospheric Chemistry and Physics, 19(4), 2115-2133. |
MLA | Guo, Liya,et al."A comprehensive study of hygroscopic properties of calcium-and magnesium-containing salts: Implication for hygroscopicity of mineral dust and sea salt aerosols".Atmospheric Chemistry and Physics 19.4(2019):2115-2133. |
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