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Morphological and mineral features of nZVI-induced precipitation on quartz particles
Liu, Fuming1,2,3; Zhou, Wan Huan1; Yi, Shuping3,4; Geng, Xueyu5
2019-05-10
Source PublicationEnvironmental Geotechnics
Volume8Issue:5Pages:357-364
Abstract

This study investigated the morphological and mineral features of nano zero-valent (nZVI)-induced iron mineral precipitation on quartz particles. Lead was employed as the artificial contaminant, while quartz was used to mimic the inert solid mineral particles in soil. The characterisation indicate that iron minerals precipitated heterogeneously on the surface of quartz particles with plush-like and flake-like structures. They are made of deuterogenic plumbiferous minerals and ferriferous minerals, with amorphous structure. The curly flake-like mineral clusters had a scattered distribution on the surface of quartz along with the corroded nZVI aggregation. The thickness of the curly flake-like precipitation varied from 20 to 60 nm, and that of the plush-like precipitation from 20 to 35 nm. The generation of these iron mineral precipitations led to a slight increase in the average particle size and a decrease in the surface area of the soil. However, no clear difference in the shape and roughness of quartz was found after the nZVI treatment. This study was performed to improve the understanding of mass transfer from nZVI to inert solid particles in soil and its effect on soil improvement.

KeywordEnvironmental Engineering Geochemistry Soil Stabilisation
DOI10.1680/jenge.18.00081
URLView the original
Language英語English
WOS IDWOS:000686473400007
Scopus ID2-s2.0-85113270135
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Document TypeJournal article
CollectionDEPARTMENT OF CIVIL AND ENVIRONMENTAL ENGINEERING
Affiliation1.Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Macao
2.Shenzhen Key Laboratory of Soil and Groundwater Pollution Control, Shenzhen, China
3.School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen, China
4.Guangdong Provincial Key Laboratory of Soil, Groundwater Pollution Control, Shenzhen, China
5.School of Engineering, University of Warwick, Coventry, United Kingdom
First Author AffilicationFaculty of Science and Technology
Recommended Citation
GB/T 7714
Liu, Fuming,Zhou, Wan Huan,Yi, Shuping,et al. Morphological and mineral features of nZVI-induced precipitation on quartz particles[J]. Environmental Geotechnics, 2019, 8(5), 357-364.
APA Liu, Fuming., Zhou, Wan Huan., Yi, Shuping., & Geng, Xueyu (2019). Morphological and mineral features of nZVI-induced precipitation on quartz particles. Environmental Geotechnics, 8(5), 357-364.
MLA Liu, Fuming,et al."Morphological and mineral features of nZVI-induced precipitation on quartz particles".Environmental Geotechnics 8.5(2019):357-364.
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