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Origins and influences of metallic lead in perovskite solar cells
Liang, Jiwei1,2; Hu, Xuzhi1; Wang, Chen1; Liang, Chao3; Chen, Cong1; Xiao, Meng1; Li, Jiashuai1; Tao, Chen1,2; Xing, Guichuan3; Yu, Rui1; Ke, Weijun1,2; Fang, Guojia1,2
2022-04-12
Source PublicationJoule
ISSN2542-4351
Volume6Issue:4Pages:816-833
Abstract

Metallic lead (Pb) impurities in metal-halide perovskites have attracted tremendous research concerns owing to their detrimental effects on perovskite solar cells (PSCs). However, the origins and influences of the Pb behind this issue have yet to be well understood. Herein, we show that Pb is hardly formed in the growth of halide perovskites but is easily postformed in the perovskite films with excess PbI. It is found that Pb impurities are decomposition byproducts of residual PbI in perovskites under light or X-ray irradiation. Therefore, PSCs obtained using photodegraded PbI films show large efficiency and stability losses. By contrast, the perovskite devices without detectable Pb impurities have a much better efficiency and stability. This work reveals the origins and influences of Pb in halide perovskites and provides a strategy for avoiding the formation of detrimental Pb byproducts, which would drive further enhancements in device performance of halide perovskite solar cells, detectors, etc.

KeywordMetallic Lead Perovskite Solar Cells Light Decomposition X-ray Irradiation Stability
DOI10.1016/j.joule.2022.03.005
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000798575600013
Scopus ID2-s2.0-85128282161
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Cited Times [WOS]:301   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorYu, Rui; Ke, Weijun; Fang, Guojia
Affiliation1.Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education of China, School of Physics and Technology, Wuhan University, Wuhan 430072, People’s Republic of China
2.Shenzhen Institute, Wuhan University, Shenzhen 518055, People’s Republic of China
3.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Macau 999078, People’s Republic of China
Recommended Citation
GB/T 7714
Liang, Jiwei,Hu, Xuzhi,Wang, Chen,et al. Origins and influences of metallic lead in perovskite solar cells[J]. Joule, 2022, 6(4), 816-833.
APA Liang, Jiwei., Hu, Xuzhi., Wang, Chen., Liang, Chao., Chen, Cong., Xiao, Meng., Li, Jiashuai., Tao, Chen., Xing, Guichuan., Yu, Rui., Ke, Weijun., & Fang, Guojia (2022). Origins and influences of metallic lead in perovskite solar cells. Joule, 6(4), 816-833.
MLA Liang, Jiwei,et al."Origins and influences of metallic lead in perovskite solar cells".Joule 6.4(2022):816-833.
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