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Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite
Zhang, Jiesong1; Wu, Jian Fang1; Wang, Zixing1; Mo, Ying1; Zhou, Wang1; Peng, Yufan1; He, Bingchen2; Xiao, Kuikui1; Chen, Shi2; Xu, Chaohe3; Liu, Jilei1
2022-08-01
Source PublicationJournal of Energy Chemistry
ISSN2095-4956
Volume71Pages:344-350
Abstract

The poor cycling stability of graphite in traditional ester electrolyte limits its applications as anodes for potassium ion batteries (KIBs). Herein, we demonstrate that the introduction of cyclic ether co-solvents into ester electrolytes can remarkably enhance the cycling stability of graphite anodes. The graphite anode in ester electrolyte with cyclic ether could achieve a reversible capacity of 196.1 mAh g after 100 cycles at 0.3 C (1 C = 280 mA g), about three times higher than those in ester electrolytes with or without linear ether. Compared with the SEI formed in ester electrolytes, the addition of tetrahydrofuran promotes the generation of KCO and ethylene oxide oligomers (PEO), of which the KCO is expected to be more conductive and PEO is mechanically robust. The more uniform, conductive and stable solid electrolyte interphases (SEIs) on graphite in electrolytes with cyclic ethers contribute to the enhancement of the electrochemical performances of graphite. This work provides a novel design of commercialized electrolytes to achieve high-performance anodes for KIBs, which potentially accelerates the development of KIBs.

KeywordCyclic Ether Graphite Potassium Ion Batteries Solid Electrolyte Interphase
DOI10.1016/j.jechem.2022.03.021
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Energy & Fuels ; Engineering
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS IDWOS:000798823400001
PublisherELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS
Scopus ID2-s2.0-85129337201
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Co-First AuthorZhang, Jiesong; Wu, Jian Fang
Corresponding AuthorXiao, Kuikui; Xu, Chaohe; Liu, Jilei
Affiliation1.College of Materials Science and Engineering, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, Hunan, 410082, China
2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Avenida da Universidade, Macau, 999078, China
3.College of Aerospace Engineering, Chongqing University, Chongqing, 400044, China
Recommended Citation
GB/T 7714
Zhang, Jiesong,Wu, Jian Fang,Wang, Zixing,et al. Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite[J]. Journal of Energy Chemistry, 2022, 71, 344-350.
APA Zhang, Jiesong., Wu, Jian Fang., Wang, Zixing., Mo, Ying., Zhou, Wang., Peng, Yufan., He, Bingchen., Xiao, Kuikui., Chen, Shi., Xu, Chaohe., & Liu, Jilei (2022). Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite. Journal of Energy Chemistry, 71, 344-350.
MLA Zhang, Jiesong,et al."Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite".Journal of Energy Chemistry 71(2022):344-350.
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