Residential College | false |
Status | 已發表Published |
Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite | |
Zhang, Jiesong1; Wu, Jian Fang1; Wang, Zixing1; Mo, Ying1; Zhou, Wang1; Peng, Yufan1; He, Bingchen2; Xiao, Kuikui1; Chen, Shi2; Xu, Chaohe3; Liu, Jilei1 | |
2022-08-01 | |
Source Publication | Journal of Energy Chemistry |
ISSN | 2095-4956 |
Volume | 71Pages:344-350 |
Abstract | The poor cycling stability of graphite in traditional ester electrolyte limits its applications as anodes for potassium ion batteries (KIBs). Herein, we demonstrate that the introduction of cyclic ether co-solvents into ester electrolytes can remarkably enhance the cycling stability of graphite anodes. The graphite anode in ester electrolyte with cyclic ether could achieve a reversible capacity of 196.1 mAh g after 100 cycles at 0.3 C (1 C = 280 mA g), about three times higher than those in ester electrolytes with or without linear ether. Compared with the SEI formed in ester electrolytes, the addition of tetrahydrofuran promotes the generation of KCO and ethylene oxide oligomers (PEO), of which the KCO is expected to be more conductive and PEO is mechanically robust. The more uniform, conductive and stable solid electrolyte interphases (SEIs) on graphite in electrolytes with cyclic ethers contribute to the enhancement of the electrochemical performances of graphite. This work provides a novel design of commercialized electrolytes to achieve high-performance anodes for KIBs, which potentially accelerates the development of KIBs. |
Keyword | Cyclic Ether Graphite Potassium Ion Batteries Solid Electrolyte Interphase |
DOI | 10.1016/j.jechem.2022.03.021 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
WOS ID | WOS:000798823400001 |
Publisher | ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS |
Scopus ID | 2-s2.0-85129337201 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Co-First Author | Zhang, Jiesong; Wu, Jian Fang |
Corresponding Author | Xiao, Kuikui; Xu, Chaohe; Liu, Jilei |
Affiliation | 1.College of Materials Science and Engineering, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha, Hunan, 410082, China 2.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Avenida da Universidade, Macau, 999078, China 3.College of Aerospace Engineering, Chongqing University, Chongqing, 400044, China |
Recommended Citation GB/T 7714 | Zhang, Jiesong,Wu, Jian Fang,Wang, Zixing,et al. Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite[J]. Journal of Energy Chemistry, 2022, 71, 344-350. |
APA | Zhang, Jiesong., Wu, Jian Fang., Wang, Zixing., Mo, Ying., Zhou, Wang., Peng, Yufan., He, Bingchen., Xiao, Kuikui., Chen, Shi., Xu, Chaohe., & Liu, Jilei (2022). Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite. Journal of Energy Chemistry, 71, 344-350. |
MLA | Zhang, Jiesong,et al."Stabilizing SEI by cyclic ethers toward enhanced K+ storage in graphite".Journal of Energy Chemistry 71(2022):344-350. |
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